Fine Chemical Technologies

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Vol 6, No 5 (2011)
View or download the full issue PDF (Russian)
4-8 171
Fundamental factors of the formation of scientific and philosophical world view of the great Russian scientist and thinker M.V. Lomonosov (1711-1765) are exposed. Correlation between scientific and philosophical reasoning in his creation work is analysed. His contribution to developing the national philosophy is shown.
9-20 237
The basic types of morphology of composite polymeric microspheres are considered. Methods of synthesizing polymeric microspheres containing inorganic nanoparticles are generalized
21-46 173
Traditional and improved methods of producing composite supports modified with nanolayers of fluoropolymers and polyanilines are reviewed. The methods provide the localization of the polymerization process at the surface layers of the carrier and additional functionality of the produced nanosystems. The effectiveness of the obtained materials in different fields of bioseparation and bioanalysis has been demonstrated
47-52 170
The prospects of using macromolecular nanoparticles as a part of polymer nanocomposites are considered. It is shown that introduction of these nanoobjects into polymers will enable investigating many fundamental problems connected with nanocomposite obtaining, estimation of their structure and properties, formation conditions
53-64 203
A brief review dedicated to prediction of phase morphologies of heterogeneous polymer blends with the aim of developing novel composite polymeric materials. The works discussed are performed mainly at the department of chemistry and physics of polymers and polymeric materials
65-71 158
The article presents a brief review of research in the field of film material science of functional oxides (high-temperature superconductors, ferroelectrics, piezoelectrics and pyroelectric, abrasives) synthesized in the context of chemical engineering. The apparatus is described, the general scheme of the synthesis processes is presented, the stages of phase formation and nanostructural transformations are considered, the functional characteristics of a number of film materials are given
72-86 171
Synthesis and biological activities of both cationic and neutral amphiphiles for the development of systems for nucleic acids delivery into eukaryotic cells have been discussed
87-97 204
The article provides the results of polychlorinated biphenyls and pesticides inventory in the Russian Federation and data about releases of dioxins estimated on the basis of various sources. The article contains brief information on some new technologies for polychlorinated biphenyls and pesticides disposal.
98-110 175
Review of results of quantum-chemical calculations of potential energy surfaces performed for several families of elementary reactions: 1) successive dehydrogenation of complex alanates of alkali and alkali-earth metals; 2) dissociative adsorption of hydrogen, methane and ethane molecules onto doped aluminum clusters Al@XAl11 with dopants X = B, C, Si, Ge, Li, and Ti; 3) conversion of mеthane into methanol in the presence of oxoferrylporphyrine complexes of (Fe=O)(P)(NН2) type.
111-117 177
The paper considers a number of mathematical models of chemical and chemical-engineering objects that use the concept of infinity. We allocated almost unrealizable processes, in the simulation of which infinity shows itself as a phantom. We considered also real processes that achieve the equilibrium state in a finite, but rather long time.
118-124 168
Two different flow sheets of extractive distillation for separation of acetone - methanol various composition mixture with water as the extractive agent in the traditional two-column complex and in the partially thermally coupled columns is compared. It is shown, that the complex column provides economy of heat on 11.2-19.6%.
125-134 123
The thermal and chemically initiated thermal rearrangements of dicarba-nido-undecaborates was explored by computational chemistry. It was shown that the kinetic stability of dianions of these compounds is reduced in the series 2,9 > 7,8 > 1,7 > 2,4 > 2,8 > 1,2 >2,7 > 2,3.
135-139 145
Theoretical calculations of the potential energy surfaces along the minimum energy pathway have been performed for elementary step-wise dehydration reactions of Ti tetrahydroaluminate by using the density functional (B3LYP) and coupled cluster (CCSD(T)) methods with the 6-311++G** basis set.
140-142 162
The results of styrene oxide epoxide cycle cleavage by diamines were summarized. The effect of solvent on regioselectivity in the reaction of N,N-diethylene diamine was studied. It was established that the ratio of products correlates well with polarity parameters ЕТ and АN of pure solvents.
143-145 188
Short review devoted to prediction of phase morphologies of heterogeneous polymer blends with the aim of the development of novel composite polymeric materials. The works discussed are performed mainly at the department of chemistry and physics of polymers and polymeric materials.
146-151 161
A methodology for immobilization of zinc oxide nanoparticles in polystyrene microspheres was developed. It includes the synthesis of stabilized zinc oxide nanoparticles and polymerization of styrene under conditions that enable carrying out the formation of adhesive contacts of nanoparticles in the polystyrene matrix.

ISSN 2410-6593 (Print)
ISSN 2686-7575 (Online)