Fine Chemical Technologies

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Vol 1, No 6 (2006)
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5-15 59
The overview discloses the results of development of synthetic methods and investigation of physico-chemical properties (structure, thermal, thermodynamic, electrophysical and catalytic characteristics) of a wide range of materials based on less-common elements. These involve materials prospective for application in computer memory, superionic conductors of NASICON-type phases, substrates for HTSC-films of various composition. The results of directed search and chemical design of precursors (soft chemistry routs) for fabrication of ferroelectrics, alloys and mixtures based on refractory metals of V-VII Groups in nano-dispersed state, solid solutions based on corresponding oxides and complex oxide phases are concerned
16-25 56
The possibility of phenolic oligomeric extractants utilization for the gallium and scandium extraction from the industrial products of aluminium ores processing has been studied. The technological schemes of the processes have been offered
26-31 62
The date of investigation on chemistry and technology of platinum metals in the large years are presented. The complexes of palladium(II) with macroheterocyclyc compounds are syntesited. The application of electrochemical processes for selection of platinum metals from solutions and applyed of concentrate of platinum metals is shown
32-37 50
The extraction of Pd(II) from acid solution HCl by derivate tioamide has been studied. The possibility separate Pd(II) and Pt(IV); Pd(II) and Ag(I) has been demonstration. The coordination mexanusm extraction has been suggested
38-44 59
The article presents new generation of the electrochemical equipment realizing technologies with controllable potential. The basic differences and advantages of electrochemical complex before the existing equipment are given. Examples of application electrochemical complex in technology of rare and platinum metals are given.
45-52 53
The extraction of Pd(II) from solution HCl by hydroxyoxime 5-(1,1,3,3- tetrametylbutyl)-2- hydroxybenzylphenyloxime (ABP) and mixture of hydroxyoximes with kerosene has been studied. The technological schema of Pd extraction from solution HCl with use of ABP has been suggested. The extraction metod of Pd by mixture of 1015% 5-nonyl-2-hydroxybenzylloxim (Аcorga P-50) + 57% trioctylamin (ТОА) + 810% isooctanol, with high yield in wide diaposons of acidity has been suggested
53-60 51
Polynuclear gallium and indium aquacomplexes were isolated as supramolecular compounds. Aquacomplexes and cucurbit[6]uril (СВ[6], C36H36N24O12) molecules are linked to each other through a system of hydrogen bonds between carbonyl groups of СВ[6] and aqua- or/and hydroxoligands of polycation
61-69 39
Extraction of rhenium by tertriary amines and aliphatic alcohols of various structure from acid solutions has been studied. The technology of complex extraction recycling of striping acid of copper – nickel production, that provides extraction of rhenium, has been proposed
70-72 45
Complexes of Be(II), Mg(II), Zn(II), Co(II), Pd(II), Cu(II)) with 2(diphenylacetyl)- indandione-1,3 and (2-phenyl-4-chlorphenylacetyl)indandione-1,3 are synthesized and studied by various methods. These compounds are isostructural innercoordinated salts with deprotonated ligand form
73-77 53
The stable, metastable and unstable regions of InGaAs/GaAs heterostructures to the formation of misfit dislocations were determined. The character of the strain distribution in the investigating samples has been estimated and the excess stress change in the quantum wells and barrier layers has been designed


78-81 47
A novel analogue of the biologically active peptide ProGlyPro containing an isosteric pseudopeptide bond instead of an amide one has been synthesized.
82-83 49
The condensation of formaldehyde with propane-1,3-diamine gave dimmer, trimer and tetramer of N,N'-bic(methylen)-propan-1,3-diamine CH2=NCH2CH2CH2N=CH2. Their structure was identified by 1 Н NMR and MS spectroscopy methods. The structure of the tetramer was, moreover, identified by x-ray crystallographic method
84-86 53
The condensation of three-components formaldehyde and mixture of ammonia and o-phenylenediamine gave novel 4-bеnzо-1,3,6,8-tetraazatricyclo[3.3.113,8]-4- undecane 5 а which was identified it’s structure by x-ray crystallographic and 1 Н NMR and MS spectroscopy methods

ISSN 2410-6593 (Print)
ISSN 2686-7575 (Online)