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Simulation of vapor-liquid equilibrium in system: a,g-dichlorohydrin–Α-monochlorohydrin–glycerol–hydrogen chloride–water

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. Both the experimental LLE and VLE data were compared with the correlated values obtained by means of the NRTL equation. Satisfactory agreement between the calculated values and experimental data was achieved

About the Authors

S. M. Zanaveskina
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation

Yu. A. Pisarenko
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation

G. S. Dmitriev
Karpov Scientific Research Institute of Physics and Chemistry, Moscow, 105064
Russian Federation

L. N. Zanaveskin
Karpov Scientific Research Institute of Physics and Chemistry, Moscow, 105064
Russian Federation


1. Тимофеев В.С., Серафимов Л.А. Принципы технологии основного органического и нефте-химического синтеза. М.: Высшая школа, 2003. 536 с.

2. Pitzer K.S. Thermodynamics of electrolytes. I. Theoretical basis and general equations // J. Phys. Chem. 1973. V. 77. Р. 268–277.

3. Bromley L.A. Thermodynamic properties of strong electrolytes in aqeous solutions // AIChE J. 1973. V. 19. № 2. Р. 313–320.

4. Chen C.-C. Computer simulation of chemical process with electrolytes / Submitted in partial fulfillment of the requirements for the degree of doctor of science of the Massachusetts Institute of Technology, 1980.

5. Chen С.-C., Britt H.I., Boston J.F., Evans L.B. Local composition model for excess gibbs energy of electrolyte systems: part i: single solvent, single completely dissociated electrolyte systems // AIChE J. 1982. V. 28. № 4. Р. 588–596.

6. Chen С.-C., Evans L.B. A local composition model for the excess Gibbs energy of aqueous electro-lyte systems // AIChE J. 1986. V. 32. № 3. Р. 444–459.

7. Mock B., Evans L.B., Chen С.-C. Phase equilibria in multiple-solvent electrolyte systems: A new thermodynamic model // Proceed. of the 1984 Summer Computer Simulation Conf. Р. 558.

8. Mock B., Evans L.B., Chen С.-C. thermodynamic representation of phase equilibria of mixed-solvent electrolyte systems // AlChE J. 1986. V. 32. № 10. Р. 1655–1664.

9. Chen C.-C. A segment-based local composition model for the Gibbs energy of polymer solutions // Fluid Phase Equilibria. 1993. V. 83. Р. 301–312.

10. Chen C.-C. Molecular thermodynamic model based on the polymer NRTL model for nonionic surfactant solutions // AIChE J. 1996. V. 42. Р. 3231–3240.

11. Song Y., Chen C.-C. Symmetric electrolyte nonrandom two-liquid activity coefficient model // Ind. Eng. Chem. Res. 2009. V. 48. Р. 7788–7797.

12. Aspen Documentation®, Aspen Physical Property System, Physical Property Methods and Models, 11.1.

13. Рахманкулов Д.Л., Кимсанов Б.Х., Локтионов Н.А., Дмитриев Ю.К., Чанышев Р.Р. Эпихлоргидрин. Методы получения, физические и химические свойства, технология производства. М.: Химия, 2003. 200 с.

14. Kirk-Othmer Encyclopedia of Chemical Technology. – John Wiley (4th ed.), 2001. V. 6. Р. 70–78.

15. Левинский М.И., Мазанко А.Ф., Новиков И.Н. Хлористый водород и соляная кислота. М.: Химия, 1985. 160 с.

16. Wilding W.V., Wilson L.C. Experimental results for DIPPR 1990-91 projects on phase equilibria and pure component properties, vapor–liquid and liquid–liquid equilibrium measurements on five binary mixtures // DIPPR Data Series. 1994. № 2. Р. 46–62.

17. Коган В.Б., Фридман В.М., Кафаров В.В. Равновесие между жидкостью и паром: в 2-х кн. Кн. 1. М.–Л.: Наука, 1966. 1426 с.

18. Людмирская Г.С., Барсукова Т.А., Боглмольный А.М. Равновесие жидкость – пар: справочное пособие. Л.: Химия, 1987. 336 с.

19. Othmer D.F. Composition of vapors from boiling binary solutions // Ind. Eng. Chem. 1928. № 20. Р. 743–746.

20. Sako T., Hakuta T.; Yoshitome H.J. Salt effects on vapor–liquid water systems equilibria for volatile strong electrolyte // Chem. Eng. Jpn. 1984. V. 17 (4). Р. 381–388.

21. Lu X. H., Wang Y.R., Shi J. Vapor equilibrium of hydrochloride-water binary system // J. Chem. Eng. of China Universities. 1987. V. 2(2). P. 1–12.

22. Fritz J.J., Fuget C.R. Vapor pressures of aqueous hydrogen chloride solutions, 0 to 50°C // Chem. Eng. Data Ser. 1956. V. 1. P. 10–12.

23. Coelho R., dos Santos P.G., Mafra M.R., Cardozo-Filho L., Corazza M.L. (Vapor+liquid) equilibrium for the binary systems {water+glycerol} and {ethanol+glycerol, ethyl stearate, and ethyl palmitate} at low temperatures // J. Chem. Thermodynamics. 2011. V. 43. P. 1870–1876.

24. Gruen A., Wirth T. Determination of glycerol and of the water content of glycerols from the specific weight and the boiling point // Angew. Chem. 1919. V. 32. P. 59–62.

25. Chen D.H.T., Thompson A.R. Isobaric vapor–liquid equilibria for the systems glycerol–water and glycerol–water saturated with sodium chloride // J. Chem. Eng. Data. 1970. V. 15. P. 471–474.

26. Vargaftik, N.B., Stepanov, V.G., Tarlakov, Yu.V. Vapour pressure of aqueous glycerol solutions // Rus. J. Phys. Chem. 1970. V.44. P. 1516.

27. Sokolov, N.M., Tsygankova, L.N., Zhavoronkov, N.M. The isolation of glycerine from products of the hydrogenolysis of saccharose // Khim. Prom-st. 1972. V. 48. P.96.

28. Oliveria M.B., Teles A.R.R., Queimada A.J., Coutinho J.A.P. Phase equilibria of glycerol containing systems and their description with the cubic-plus-association (CPA) equation of state // Fluid Phase Equilib. 2009. V. 280. P. 22–29.

29. Soujanya J., Satyavathi B., Vittal Prasad T.E. Experimental (vapour + liquid) equilibrium data of (methanol + water), (water + glycerol) and (methanol + glycerol) systems at atmospheric and sub-atmospheric pressures // J. Chem. Thermodyn. 2010. V. 42. P. 621–624.


For citations:

Zanaveskina S.M., Pisarenko Yu.A., Dmitriev G.S., Zanaveskin L.N. Simulation of vapor-liquid equilibrium in system: a,g-dichlorohydrin–Α-monochlorohydrin–glycerol–hydrogen chloride–water. Fine Chemical Technologies. 2013;8(2):26-33. (In Russ.)

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