Preview

Fine Chemical Technologies

Advanced search

FUNCTIONAL MODELING OF CARBON SORBENTS SYNTHESIS CONTROL

https://doi.org/10.32362/2410-6593-2019-14-1-39-46

Full Text:

Abstract

The formalized model of carbon sorbent synthesis control based on the methodology for functional modeling is constructed. The correlations between the directions of use and the properties of carbon sorbents are revealed. The characteristics that are essential regardless of the direction of use of the sorbent, in particular, sorption properties and strength are identified. The technologies based on the gas-phase method of obtaining carbon material are considered, the analysis of individual stages of the process of obtaining carbon sorbents is carried out. The analysis of the influence of the technological parameters of the synthesis on the properties of sorbents is carried out. On the basis of the established relationships, a functional model has been built that provides a hierarchically ordered, structured, visual description of the management of carbon sorbent synthesis. The simulation is performed “from top to bottom” from the most general description to the detail. The resulting model is a set of interrelated graphical diagrams. At the initial stage, the synthesis of carbon sorbent is considered as a single process, the input parameters of which are hydrocarbon gas, the activating agent and the material form factor, the output - carbon sorbent, and the control parameters are the requirements for strength and sorption properties. Then the synthesis process is decomposed. The control processes (analysis of raw material properties and matrix selection), technological processes (raw material preparation) and mixed processes are distinguished as a result of decomposition. The model includes a consistent description of the technological parameters selection (temperature, gas flow and time) for both stages of the synthesis process. The model is the base for information support providing for the production of carbon sorbents with the required properties.

About the Authors

V. V. Burlyaev
MIREA - Russian Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)
Russian Federation

Ph.D. (Engineering), Professor, Chair of Information Systems in Chemical Technology,

86, Vernadskogo pr., Moscow, 119571, Russia



E. V. Burlyaeva
MIREA - Russian Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)
Russian Federation

D.Sc. (Engineering), Professor, Chair of Information Systems in Chemical Technology,

86, Vernadskogo pr., Moscow, 119571, Russia



A. I. Nikolaev
MIREA - Russian Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)
Russian Federation

D.Sc (Engineering), Professor, A.N. Bashkirov Chair of Petrochemical Synthesis and Synthetic Liquid Fuel Technology,

86, Vernadskogo pr., Moscow, 119571, Russia



B. V. Peshnev
MIREA - Russian Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)
Russian Federation

D.Sc (Engineering), Professor, A.N. Bashkirov Chair of Petrochemical Synthesis and Synthetic Liquid Fuel Technology,

86, Vernadskogo pr., Moscow, 119571, Russia



References

1. Burlyaeva E.V., Razlivinskaya S.V., Tregubov A.V. Development and application of the generalized functional model of one-stage chemical manufacturing. Prikladnaya informatika (Journal of Applied Informatics). 2016; 11(1): 64-70. (in Russ.)

2. Recommendations for standardization. Information support technology of the life cycle product. Functional modeling methodology. Moscow: Gosstandart Publ., 2001. 19 p. (in Russ.).

3. Burlyaev V.V., Burlyaeva E.V., Nikolaev A.I., Peshnev B.V., Razlivinskaya S.V. Functional modeling of carbon nanotubes synthesis control. Vestnik MITHT (Fine Chemical Technologies). 2014; 9(3): 98-104. (in Russ.)

4. Erusheva K.I., Kolybanov K.Yu., Tishaeva I.R. Process functional modeling of the best available technique choosing. Tonkie khimicheskie tekhnologii (Fine Chemical Technologies). 2017; 12(4): 98-105. (in Russ.)

5. Mukhin V.M., Tarasov A.V., Klushin V.N. Active carbons of Russia. Moscow: Metallurgiya Publ. 2000. 352 p. (in Russ)

6. Krivonos O.I., Plaksin G.V. Porous carbonmineral materials based on sapropels. Solid Fuel Chemistry (Khimiya tverdogo topliva). 2015; 49(1): 36-40.

7. Perederiy M.A., Noskova Yu.A., Karaseva M.S., Konovalov P.N. New carbon sorbents. Khimiya tverdogo topliva (Solid Fuel Chemistry). 2009; 6: 36-46. (in Russ.)

8. Plaksin G.V., Baklanova O.N., Lavrenov A.V., Likholobov V.A. Carbon materials from the sibunit family and methods for controlling their properties. Solid Fuel Chemistry (Khimiya tverdogo topliva).. 2014; 48(6): 349-355.

9. Surovikin Y.V., Likholobov V.A., Sergeev V.V., Makarov I.V. Application of new carbon-carbon sorbents for technological solutions purifying from organic impurities in hydrometallurgy cobalt. Solid Fuel Chemistry (Khimiya tverdogo topliva). 2014; 48(6):

10. 371-381.

11. P’yanova L.G., Baklanova O.N., Likholobov V.A., Lavrenov A.V., Sedanova A.V. Modified carbon sorbents: Synthesis, properties and application. Proceedings of the 10th Int. Conf. «Carbon: Fundamental Problems of Science, Materials Science, Technology»). Russia, Moscow, Troitsk. 6–9 June 2016. P. 359. (in Russ.).

12. Surovikin V.F., Surovikin Yu.V., Tsekhanovich M.S. New trends in the technology of carbon-carbon materials obtaining. Application of carbon-carbon materials. Russian J. General Chemistry. 2007; 77(12): 2301-2310.

13. Plaksin G.V. Porous carbon materials as sibunit. Khimiya v interesah ustojchivogo razvitiya (Chemistry for Sustainable Development). 2001; 9(5): 609-620. (in Russ.).

14. Polyakov N.S., Petukhova G.A., Surovikin V.F. Adsorption properties and porous structure of new carbon materials. Izvestiya Akademii nayk (Proceedings of the Academy of Sciences. Chemical series). 1993; 8: 1377-1380. (in Russ.)

15. Surovikin Yu.V., Surovikin V.F., Tsekhanovich M.S., Lykholobov V.A. New carbon catalyst for chemical processes. Rossijskij khimicheskij zhurnal (Russian Chemical Journal). 2006; 50(1): 58-59. (in Russ.)

16. Gavrilov V.Yu., Fenelonov V.B., Chuvilin A.L., Plaksin G.V., Surovikin V.F., Ermakov Yu.I., Semikolenov V.A. The morphology and porous structure study of composite carbon-carbon materials. Khimiya tverdogo topliva (Solid Fuel Chemistry). 1990; 2: 125-129. (in Russ.)

17. Nikolaev A.I. The production of carbon-carbon composite materials based on carbon nanofibers by the gas-phase method. Tonkie himicheskie tehnologii (Fine Chemical Technologies). 2015; 10(2): 61-66. (in Russ.)

18. Syrieva A.V., Surovikin Y.V. Influence of the synthesis temperature of pyrocarbon matrix on its activation with water vapor. «Technique and technology of petrochemical and oil and gas production». Proceed. of the 7th International Scientific and Technical Conference. 2017. P. 158-159. (in Russ.)

19. Nguyen V.H., Filimonov A.S., Peshnev B.V., Nikolaev A.I. Oxidation of disperse carbon materials. Tonkie khimicheskie tekhnologii (Fine Chemical Technologies). 2018; 13(3): 57-63. (in Russ.)

20. Peshnev B.V., Filimonov A.S., Gavrilova N.N., Nikolaev A.I., Nguyen V.Kh. Carbon materials production with a given porosity. Khimiya tverdogo topliva (Solid Fuel Chemistry). 2018; 3: 35-40. (in Russ.)

21. Peshnev B.V., Filimonov A.S., Baulin S.V., Sledz O.S., Asilova N.Yu. The pyrocarbon formation mechanism during the hydrocarbon pyrolysis process. Tonkie khimicheskie tekhnologii (Fine Chemical Technologies). 2017: 12(4): 36-42. (in Russ.).


Supplementary files

1. Detailed description of the synthesis of carbon sorbent
Subject
Type Research Instrument
View (100KB)    
Indexing metadata

Review

For citations:


Burlyaev V.V., Burlyaeva E.V., Nikolaev A.I., Peshnev B.V. FUNCTIONAL MODELING OF CARBON SORBENTS SYNTHESIS CONTROL. Fine Chemical Technologies. 2019;14(1):39-46. (In Russ.) https://doi.org/10.32362/2410-6593-2019-14-1-39-46

Views: 458


ISSN 2410-6593 (Print)
ISSN 2686-7575 (Online)