To the question of aggregative stability of latex stabilized by the mixture of non-ioniq and anionic surfactants
Abstract
The colloid properties of styrene-butadiene latex stabilysed by the mixture of anionic alkylsulphonat (AS) and non-ionic oxiethylated fat alcohole (OC-20) were investigated. Addition of little amounts (less than 0,2 mol. Part) of AS into the mixture was founed to lead to the non-additive changes in particle sizes, influence the thickness of adsorbtion layers, Z-potencial and latex viskosity. It was shown that an agregative stability of the latex in the presents of different destabilizating factors (addition of electrolites, increasing of temperature, freezing, mechanical stiring) can be controlled, depending of their practical use, by changing the emulsifier mixture composition. For example, by changing the AS content in the composition one can reach the different thermosensibility of latex.
About the Authors
T. S. Solovieva
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation
N. N. Ivanova
Plekhanov Russian University of Economics, Moscow, 117997
Russian Federation
References
1. Ланге К.Р. Поверхностно-активные вещества: синтез, свойства, анализ, применение. Перевод с англ. СПб, изд. «Профессия», 2005 г., 218 с.
2. Практикум по коллоидной химии и электронной микроскопии, под ред. С.С. Воюцкого, Р.М. Панич, М. Химия, 1974, 224 с.
3. Еркова Л.Н., Чечик О.С. Латексы, Л. Химия, 1983, 223 с.
4. Рейхсфельд В.О., Еркова Л.Н., Рубан В.Л. Практикум по синтетическим каучукам, Л. Химия, 1967, 228с.
5. Вережников В.Н. Дисс. докт. хим. наук, МИТХТ, М. 1993.
For citations:
Solovieva T.S.,
Ivanova N.N.
To the question of aggregative stability of latex stabilized by the mixture of non-ioniq and anionic surfactants. Fine Chemical Technologies. 2006;1(2):46-50.
(In Russ.)
Views:
307