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A COATING BASED ON CROSS-LINkED POLyDIMETHyLSILOXANE AND NANOPARTICLES WITH DIFFERENT MORFOLOGIES FOR SUPERHyDROPHBIC TEXTILE FABRICATION

https://doi.org/10.32362/2410-6593-2017-12-3-65-72

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Abstract

A composition and method for applying a superhydrophobic composite coating for fabrics based on chemically crosslinked polydimethylsiloxane (PDMS), silica nanoparticles (SiO2 NP), composite nanoparticles with “polystyrene core/silica shell structure” and a fluoroalkylsilane (FAS) were proposed. It is shown that the degree of hydrophobicity and durability of the composition are the functions of NP, PDMS and FAS concentration and their ratios. The optimal concentrations of the components for the formation of a coating with a maximum degree of hydrophobicity (water static and sliding contact angle ≈ 170° and 2°, respectively) were determined. It is established that the developed composition is characterized by prolonged wear resistance to various types of abrasive action, heat treatment, exposure to acids and bases. It was experimentally determined that the observed effects are a consequence of the complex influence of all the constituents of the composition.

About the Author

V. V. Terekhin
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences
Russian Federation
Moscow 119071, Russia


References

1. Zhang D., Wang L., Qian H., Li X. Superhydrophobic surfaces for corrosion protection: a review of recent progresses and future directions // J. Coat. Technol. Res. 2016. V. 13. P. 11–29.

2. Cohen N., Dotan A., Dodiuk H., Kenig S. Thermomechanical mechanisms of reducing ice adhesion on superhydrophobic surfaces // Mater. & Manufact. Proc. 2016. V. 32. P. 9664–9675.

3. Park S., Kim J., Park C.H. Breathable, antistatic and superhydrophobic PET/Lyocell fabric // J. Eng. Fibers and Fabrics. 2015. V. 10. P. 1– 18.

4. Pan Q., Wang M., Wang H. Separating small amount of water and hydrophobic solvents by novel superhydrophobic copper meshes // Appl. Surf. Sci. 2008. V. 254. P. 6002–6006.

5. Wang C., Yao T., Wu J., Ma C., Fan Z., Wang Z., Cheng Y., Lin Q., Yang B. Facile approach in fabricating superhydrophobic and superoleophilic surface for water and oil mixture separation // ACS Appl. Mater. Interfaces. 2009. V. 1. P. 2613–2617.

6. Michael N., Bharat B. Energy transitions in superhydrophobicity: low adhesion, easy flow and bouncing // J. Phys.: Condensed Matter. 2008. V. 20. P. 395005.

7. Mishchenko L., Hatton B., Bahadur V., Taylor J.A., Krupenkin T., Aizenberg J. Design of ice-free nanostructured surfaces based on repulsion of impacting water droplets // ACS Nano. 2010. V. 4. P. 7699–7707.

8. She Z., Li Q., Wang Z., Li L., Chen F., Zhou J. Researching the fabrication of anticorrosion superhydrophobic surface on magnesium alloy and its mechanical stability and durability // Chem. Eng. J. 2013. V. 228. P. 415–424.

9. Chen Y., Chen S., Yu F., Sun W., Zhu H., Yin Y. Fabrication and anti-corrosion property of superhydrophobic hybrid film on copper surface and its formation mechanism // Surf. Interf. Anal. 2009. V. 41. P. 872–877.

10. Kulinich S., Farhadi S., Nose K., Du X.W. Superhydrophobic surfaces: Are they really icerepellent? // Langmuir. 2011. V. 27. P. 25–29.

11. Shi F., Niu J., Liu J., Liu F., Wang Z., Feng X. Q., Zhang X. Towards understanding why superhydrophobic coating is needed by water strider // Adv. Mater. 2007. V. 19. P. 2257– 2261.

12. Zimmermann J., Reifler F. A., Fortunato G., Gerhardt L.-C., Seeger S. A simple, one-step approach to durable and robust superhydrophobic textiles // Adv. Funct. Mater. 2008. V. 18. P. 3662–3669.

13. Deng B., Cai R., Yu Y., Jiang H., Wang C., Li J., Li L., Yu M., Li J., Xie L., Huang Q., Fan C. Laundering durability of superhydrophobic cotton fabric // Adv. Mater. 2010. V. 22. P. 5473–5477.

14. Wang H., Xue Y., Ding J., Feng L., Wang X., Lin T. Durable, self-healing superhydrophobic and superoleophobic surfaces from fluorinated-decyl polyhedral oligomeric silsesquioxane and hydrolyzed fluorinated alkyl silane // Angew. Chem. Int. Ed. 2011. V. 50. P. 11433–11436.

15. Blunt L., Jiang X., Scott P.G. Advanced techniques for assessment surface topography: development of a basis for 3D surface texture standards “surfstand”. London: Kogan Page Science. 2003. 355 p.

16. Barthlott W., Neinhuis C. Purity of the sacred lotus, or escape from contamination in biological surfaces // Planta. 1997. V. 202. P. 1–8.

17. Terekhin V.V., Shashkova O.B. Composite particles with the structure of "polystyrene-core/SiO2- shell" and mesoporous SiO2-capsules based on them: Synthesis and release of the loaded substance // Kolloidnyi zhurnal (Colloid Journal). 2016. V. 78. P. 789–798. (in Russ.).


Review

For citations:


Terekhin V.V. A COATING BASED ON CROSS-LINkED POLyDIMETHyLSILOXANE AND NANOPARTICLES WITH DIFFERENT MORFOLOGIES FOR SUPERHyDROPHBIC TEXTILE FABRICATION. Fine Chemical Technologies. 2017;12(3):65-72. (In Russ.) https://doi.org/10.32362/2410-6593-2017-12-3-65-72

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ISSN 2410-6593 (Print)
ISSN 2686-7575 (Online)