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Preceramic monomers for silicon carbonitride and nitride production by means of chemical vapor deposition

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Abstract

Tris(N-methyl)trimethylcyclotrisilazane (cyclosilazane-1) and tetra(N-methyl)tetramethylcyclotetrasilazane (cyclosilazane -2), that are promising preceramic monomers for the production of oxygen-proof materials based on silicon carbonitride and nitride by СVD and CVI, were obtained through methyldichlorosilane aminolysis, isolated and characterized by 1Н, 29Si NMR and gas-liquid chromatography. The conducted research resulted in the identification of factors effecting the reaction direction. According to solvent nature the reaction may be directed either towards cyclosilazane-1 formation or cyclosilazane-2 formation. In terms of efficiency, that is defined as cyclosilazane-1 to cyclosilazane-2 ratio, the solvents may be arranged in the following sequence: rubber solvent > rubber solvent + DE (diethyl ether) > nefras + DE > dichloromethane + DE > benzene.

About the Authors

O. G. Ryzhova
ФГУП ГНИИХТЭОС
Russian Federation


A. A. Grigoryev
ФГУП ГНИИХТЭОС
Russian Federation


P. А. Storozhenko
ФГУП ГНИИХТЭОС
Russian Federation


A. N. Polivanov
ФГУП ГНИИХТЭОС
Russian Federation


S. V. Zhukova
ФГУП ГНИИХТЭОС
Russian Federation


T. I. Shulyatyeva
ОАО «Композит»
Russian Federation


I. A. Timofeev
ОАО «Композит»
Russian Federation


Е. А. Bogachev
ОАО «Композит»
Russian Federation


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For citation:


Ryzhova O.G., Grigoryev A.A., Storozhenko P.А., Polivanov A.N., Zhukova S.V., Shulyatyeva T.I., Timofeev I.A., Bogachev Е.А. Preceramic monomers for silicon carbonitride and nitride production by means of chemical vapor deposition. Fine Chemical Technologies. 2012;7(2):51-57. (In Russ.)

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ISSN 2410-6593 (Print)
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