Preview

Fine Chemical Technologies

Advanced search

Synthesis of ethyl acetate by dehydrogenation of ethanol. Process study. Technological aspects

Abstract

Experimental data of a study on the synthesis of ethyl acetate by catalytic dehydrogenation of ethanol are presented. Tests of the catalyst were carried out in a flow reactor at a temperature of 230–300 ° С and under a pressure of 0.1–2.0 MPa. Industrial catalyst NTK-4 was used. Conversion of ethanol was 40–63%, selectivity was 86–94%. In the process hydrogen is produced, and it can be used on one of the stages of the process. Some technological aspects are also presented.

About the Authors

I. P. Semenov
МИТХТ им. М.В. Ломоносова
Russian Federation


Yu. A. Pisarenko
МИТХТ им. М.В. Ломоносова
Russian Federation


V. A. Menshchikov
ООО «ТЕХНОЛОГИИ ВНИИОС»
Russian Federation


References

1. Этилацетат (ETAC): Обзор рынка 2011 и прогноз на 2012-2016 гг. – Merchant Research and Consulting Ltd.

2. Чащин А.М., Глухарева М.И. Ацетатные растворители в лесохимической промышленности. – М.: Лесн. пром-сть, 1988. 152 c.

3. Каррер П. Курс органической химии: пер. с нем. – Л.: Гос. научно-техн. изд-во хим. лит-ры, 1962. 620 с.

4. Kanichiro Inui, Satoshi Sato. Effective formation of ethyl acetate from ethanol over Cu-Zn-Zr-Al-O catalyst / J. Mol. Catalysis A: Chemical. 2004. V. 216. № 1. P. 147–156.

5. Elliott D.L., Pennella F. Effects of transition metals on Cu/ZnO alcohol synthesis catalysts // J. Catal. 1989. V. 119. Р. 359–367.

6. Bolder F.M.A. Dehydrogenation of alcohol mixtures to esters and ketones // Ind. And Eng. Chem. Res. 2008. V. 47. № 19. Р. 7496–7500.


Review

For citations:


Semenov I.P., Pisarenko Yu.A., Menshchikov V.A. Synthesis of ethyl acetate by dehydrogenation of ethanol. Process study. Technological aspects. Fine Chemical Technologies. 2012;7(5):52-56. (In Russ.)

Views: 870


ISSN 2410-6593 (Print)
ISSN 2686-7575 (Online)