Simple diffusion model of cage effect
Abstract
On the assumption of the initial Gaussian distribution of the inter-radical distances the dependence of the radical combination probability in a solvent cage on the viscosity and temperature was derived. The dependence describes the published data correctly and may be used for the initial inter-radical distances estimation in different radical pairs.
About the Author
E. I. Finkelshteyn
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation
Russian Federation
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Finkelshteyn E.I. Simple diffusion model of cage effect. Fine Chemical Technologies. 2014;9(6):69-74. (In Russ.)
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