Using nitrogen-containing organosilicon compounds in the creation of heat- and fire-resistant filling compositions to seal high-voltage and high-frequency equipment
https://doi.org/10.32362/2410-6593-2024-19-4-293-309
EDN: ZVSAGK
Abstract
Objectives. To study the possibility of using nitrogen-containing organosilicon compounds in the creation of heat-resistant and fireresistant casting compositions to seal high-voltage high-frequency equipment.
Methods. Nitrogen-containing organosilicon compounds were obtained using the N-siloxycarbonylation, formylation, and silylation methods. The methods used in the work were infrared spectroscopy, elemental analysis, viscometry, and differential scanning calorimetry. The mechanical and dielectric properties of the samples were determined.
Results. Previously unknown substances and compounds containing nitrogen-containing organosilicon products as components of the curing composition were obtained. Their physicomechanical and operational properties were examined, including the possibility of using them as filling heat-resistant and fire-resistant compositions for sealing high-voltage and high-frequency equipment.
Conclusions. It was shown that nitrogen-containing organosilicon compounds — 3-(diethylamino)-2-[(triethoxysilyl)oxy]propyl-2-methacrylate and triethoxysilyl ester of γ-triethoxysilylpropyl-carbamic acid — can be used as part of a curing system together with bromine-containing fillers, in order to obtain compounds used for filling high-voltage high-frequency transformers, throttle valves, and other electronic equipment elements with non-combustible properties and increased heat resistance.
About the Authors
A. D. KirilinRussian Federation
Alexey D. Kirilin - Dr. Sci. (Chem.), Professor, Head of the K.A. Andrianov Department of Chemistry and Technology of Organoelement Compounds, M.V. Lomonosov Institute of Fine Chemical Technologies. Scopus Author ID 6603604447, ResearcherID О-9744-215.
86, Vernadskogo pr., Moscow, 119571
Competing Interests:
The authors declare that there is no conflict of interest
L. O. Belova
Russian Federation
Liya O. Belova - Dr. Sci. (Chem.), Professor, K.A. Andrianov Department of Chemistry and Technology of Organoelement Compounds, M.V. Lomonosov Institute of Fine Chemical Technologies. Scopus Author ID 7102282244.
86, Vernadskogo pr., Moscow, 119571
Competing Interests:
The authors declare that there is no conflict of interest
N. A. Golub
Russian Federation
Nataliya A. Golub - Cand. Sci. (Chem.) Associate Professor, K.A. Andrianov Department of Chemistry and Technology of Organoelement Compounds, M.V. Lomonosov Institute of Fine Chemical Technologies, Scopus Author ID 56084643600.
86, Vernadskogo pr., Moscow, 119571
Competing Interests:
The authors declare that there is no conflict of interest
M. V. Pletneva
Russian Federation
Mariya V. Pletneva - Cand. Sci. (Chem.) Associate Professor, K.A. Andrianov Department of Chemistry and Technology of Organoelement Compounds, M.V. Lomonosov Institute of Fine Chemical Technologies, Scopus Author ID 37104888400.
86, Vernadskogo pr., Moscow, 119571
Competing Interests:
The authors declare that there is no conflict of interest
N. I. Kirilina
Russian Federation
Nadezhda I. Kirilina - Cand. Sci. (Chem.), Leading Engineer, Scopus Author ID 57193056863.
38, Entuziastov shosse, Moscow, 111123
Competing Interests:
The authors declare that there is no conflict of interest
D. E. Mironov
Russian Federation
Denis E. Mironov - Postgraduate Student, K.A. Andrianov Department of Chemistry and Technology of Organoelement Compounds, M.V. Lomonosov Institute of Fine Chemical Technologies.
86, Vernadskogo pr., Moscow, 119571
Competing Interests:
The authors declare that there is no conflict of interest
References
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Supplementary files
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1. Temperature dependence of tgδ and ɛ' on the type of hardener at a frequency of 1000 Hz | |
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- Previously unknown substances and compounds containing nitrogen-containing organosilicon products as components of the curing composition were obtained. Their physicomechanical and operational properties were examined, including the possibility of using them as filling heat-resistant and fire-resistant compositions for sealing high-voltage and high-frequency equipment.
- It was shown that nitrogen-containing organosilicon compounds—3-(diethylamino)-2-[(triethoxysilyl)oxy]propyl-2-methacrylate and triethoxysilyl ester of γ-triethoxysilylpropyl-carbamic acid—can be used as part of a curing system together with bromine-containing fillers, in order to obtain compounds used for filling high-voltage high-frequency transformers, throttle valves, and other electronic equipment elements with non-combustible properties and increased heat resistance.
Review
For citations:
Kirilin A.D., Belova L.O., Golub N.A., Pletneva M.V., Kirilina N.I., Mironov D.E. Using nitrogen-containing organosilicon compounds in the creation of heat- and fire-resistant filling compositions to seal high-voltage and high-frequency equipment. Fine Chemical Technologies. 2024;19(4):293-309. https://doi.org/10.32362/2410-6593-2024-19-4-293-309. EDN: ZVSAGK