COMPETITION OF OXYGEN- AND NITROGEN-DONOR LIGANDS IN THE SYNTHESIS OF COMPLEX COMPOUNDS OF COPPER WITH 2-(PHENYL-4-CHLOROPHENYLACETYL)INDANDIONE-1,3
https://doi.org/10.32362/2410-6593-2018-13-6-60-68
Abstract
The interaction of CuCl and 2-(phenyl-4-chlorophenylacetyl)indandione-1,3 (HL, C23H15ClO3) in a mixed organic solvent (CH3CN, C5H5N, EtOH) gave a solvated crystal complex of copper(II) of composition [Cu(C2H5OH)(L)2]•C2H5OH (I). The isolated compound was investigated by X-ray and IR spectroscopy methods. Lattice parameters of (I): space gr. P21/c, a = 14.982(1), b = 14.558(1), с = 20.608(2) Å; β= 105.176(2)°; Z = 4 (Z′=1). It is established that the structural units in the crystal structure of the obtained compounds are the neutral square-planar coordination spheres of Cu(II) with cis-oriented deprotonated indandionate ligands L. The spheres are located in the space pairwise. One molecule of EtOH is included in the internal sphere of the complex, and the second is a bridge that unites the coordination centers due to the hydrogen bonds between the hydrogen atom of the hydroxo group of the coordinated alcohol and the O-atom of the keto group of the adjacent bis-chelate. This results in a dimer structure. At the same time, in addition to ethanol, molecules of other co-solvents (CH3CN, C5H5N) do not participate in complex formation and do not form solvates. It was found that a copper(II) complex is formed from copper(I) chloride. When using copper(I) iodide as a starting compound in ethanol in the presence of pyridine the formation of the chelate with the deprotonated ligand HL is not observed.
Keywords
2-(ацетил)индандион-1,3,
2-(дифенилацетил)индандион-1,3,
2-(фенил-4-хлорфенилацетил)индандион-1,3,
copper(I),
copper(II),
coordination compounds,
2-(acetyl)indandion-1,3,
2-(diphenylacetyl)indandion-1,3,
2-(phenyl-4-chlorophenylacetyl)indandione-1,3,
cyclic tricarbonyl compounds,
IR spectroscopy
About the Authors
L. A. Nosikova
MIREA - Russian Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)
Russian Federation
Russian Federation
Ph.D. (Chemistry), Associate Professor, K.A. Bolshakov Chair of Chemistry and Technology of Rare and Scattered Elements, Nanoscale and Composite Materials
86, Vernadskogo Pr., Moscow 119571, Russia
ResearcherID: 679715
A. N. Kochetov
MIREA - Russian Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)
Russian Federation
Russian Federation
Ph.D. (Chemistry), Senior Lecturer, A.N. Reformatsky Chair of Inorganic Chemistry
86, Vernadskogo Pr., Moscow 119571, Russia
ResearcherID: 213376
Z. A. Kudryashova
MIREA - Russian Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)
Russian Federation
Russian Federation
Ph.D. (Chemistry), Associate Professor, A.N. Reformatsky Chair of Inorganic Chemistry
86, Vernadskogo Pr., Moscow 119571, Russia
A. Yu. Tsivadze
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences (IPCE RAS)
Russian Federation
Russian Federation
Academician, D.Sc. (Chemistry), Professor, Head of the Laboratory of New Physicochemical Problems
31 Leninsky prospect, Moscow 119071, Russia
ResearcherID: G-7422-2014
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Review
For citations:
Nosikova L.A., Kochetov A.N., Kudryashova Z.A., Tsivadze A.Yu. COMPETITION OF OXYGEN- AND NITROGEN-DONOR LIGANDS IN THE SYNTHESIS OF COMPLEX COMPOUNDS OF COPPER WITH 2-(PHENYL-4-CHLOROPHENYLACETYL)INDANDIONE-1,3. Fine Chemical Technologies. 2018;13(6):60-68. (In Russ.) https://doi.org/10.32362/2410-6593-2018-13-6-60-68
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