Ruthenium: Past and Present
https://doi.org/10.32362/2410-6593-2019-14-6-22-30
Abstract
This article provides information on one of the most interesting elements in the D.I. Mendeleev Periodic Table - ruthenium, discovered 175 years ago by the outstanding Russian chemist Karl Karlovich Klaus. Its most important physical properties, a variety of oxidation states, and a tendency to form countless compounds have been noted, mocking it unique and indispensable in all areas of science, technology, and in society. We have taken into consideration the structure of ruthenium consumption today as well as a few prospects for its future use.
About the Authors
T. M. BuslaevaRussian Federation
Tatyana M. Buslaeva - Dr. of Sci. (Chemistry), Professor, Professor of the К.А. Bolshakov Department of Chemistry and Technology of Rare and Scattered Elements, Nanoscale and Composite Materials, ResearcherID R-7445-2016, Scopus Author ID 6602442002.
86, Vernadskogo pr., Moscow 119571
Competing Interests: no conflicts of interest
E. V. Fesik
Russian Federation
Elena V. Fesik - Cand. of Sci. (Chemistry), Associate Professor of the К.А. Bolshakov Department of Chemistry and Technology of Rare and Scattered Elements, Nanoscale and Composite Materials, ResearcherID C-85252014, Scopus Author ID 36668429900.
86, Vernadskogo pr., Moscow 119571
Competing Interests: no conflicts of interest
N. A. Khan
Russian Federation
Nadezhda A. Khan – Student.
86, Vernadskogo pr., Moscow 119571
Competing Interests: no conflicts of interest
References
1. Menshutkin B.N. Karl Karlovich Klaus. Proceedings of the Institute for the Study of Platinum and Other Noble Metals. 1928;6:1-10 (in Russ.).
2. Ushakova N.N. Karl Karlovich Klaus (Karl Ernst Claus). Moscow: Nauka; 1972. 150 p.
3. Fedorenko N.V. Razvitie issledovanii platinovykh metallov v Rossii (Development of research of platinum metals in Russia). Moscow: Nauka; 1985. 264 p. (in Russ.).
4. Buslaeva T.M. (Ed.). Russkii element (Russian element). Moscow: M.V Lomonosov MITHT Publishing House; 2014. 192 p. (in Russ.).
5. Klaus K.K. Izbrannye trudy po khimii platinovykh metallov (Selected Works on the Chemistry of Platinum Metals). Moscow: Publishing House of the USSR Academy of Sciences; 1954. 304 p. (in Russ.).
6. Seddon E.A., Seddon K.R. The Chemistry of Ruthenium. New York: Elsevier, 1984. 1373 p.
7. Tretyakov Yu.D. (Ed.) Neorganicheskaya khimiya v 3-kh t. (Inorganic chemistry in 3 v.) Moscow: Publishing Center Akademiya; 2007. 352 p. (in Russ.).
8. Rytvin E.I. Zharoprochnost’ platinovykh splavov (Heat resistance of platinum alloys). Moscow: Publ. House Ruda i metally; 2012. 264 p. (in Russ.).
9. Lazarev V.B., Krasov V.G., Shaplygin I.S. Elektroprovodnost’ okisnykh sistem i plenochnykh struktur (Electrical conductivity of oxide systems and film structures). Moscow: Nauka, 1979. 168 p. (in Russ.).
10. Eberil VI., Fedotova N.S., Novikov E.A. Polarization characteristics of ORTA anodes under conditions of sodium chlorate production. Elektrokhimiya = Russian Journal of Electrochemistry. 1990;33(5):610-616. (in Russ.).
11. Hugon M. (Ed.). Overview of the EU research projects on partitioning and transmutation of long-live radionuclides. Nuclear science and technology, EUR 19614 EN. Luxembourg: Office for Official Publication of the European Communities, 2001. 68 p.
12. Belyaev A.V, Renard E.V, Khranenko S.P., Emel’yanov V.A., Fedotov M.A. State of radiorhodium in high-level liquid waste from the regeneration of spent nuclear fuel. Radiokhimiya = Radiochemistry. 2002;44(6):546-558.
13. Greenwood N.N. Ernshaw A. Khimiya elementov: v 2 t. (Chemistry of elements: in 2 v.) Moscow: BINOM. Laboratoriya znanii, 2008. 666 p. (in Russ.).
14. Yagubskii E.B., Kushch L.A. Bifunctional compounds based on transition metal mononitrosyl complexes combining photochromism and electrical conductivity or photochromism and magnetism. Rossiiskie nanotekhnologii = Nanotechnologies in Russia. 2009;3(3-4):151-165. https://doi.org/10.1134/S1995078008030026
15. Daguenet C., Scopelleti R., Dyson P.J. Mechanistics investigations of the hydrogenation of alkenes using ruthenium(II)-arene diphosphine complexes. Organometallics. 2004;23(21):4849-4857. https://doi.org/10.1021/om049665q
16. Buslaeva T.M., Redkina S.N., Kiseleva I.N. Interaction of ruthenium (III) and (IV) chlorocomplexes with acetic acid. Koordinatsionnaya khimiya = Russian J. Coord. Chemistry. 1995;21(1):42-46. (in Russ.).
17. Malchikov G.D., Fesik E.V The autoclave method for producing ruthenium-containing catalysts and the study of their catalytic properties. In: Materialy XVIII Mezhdunarodnoi Chernyaevskoi konferentsii po khimii, analizu i tekhnologii platinovykh metallov = Proceedings of the XVIII International Chernyaev Conference on Chemistry, Analysis and Technology of Platinum Metals: Abstracts. Moscow, Russia, September 8 - 13, 2006. P. 162-163. (in Russ.)
18. Fesik E.V, Zarazhevskii V.I., Grebnev VV., Mal'chikov G.D. Rhenium- and ruthenium-containing catalysts for neutralization of automobile exhaust. Kinetika i kataliz = Kinet Catal. 2013;54(5):626-631. https://doi.org/10.1134/S0023158413050054
19. E)iaz-Valenzuela M.B., Phillips S.D., France M.B., Gunn M.E., Clarke M.L. Enantioselective hydrogenation and transfer hydrogenation of bulky ketones catalysed by ruthenium complex of a chiral tridentate ligand. Chem. Eur. J. 2009;15(5):1227-1232. https://doi.org/10.1002/chem.200801929
20. Tzur E., Szadhowska A., Ben-Asuly A., Goldberg I., Wozniak K., Grela K., Lemcoff N.G. Studies of electronic effects in O-, N- and S-chelated ruthenium olefin-metathesis catalysts. Chemistry. 2010;16(29):8726-8737. https://doi.org/10.1002/chem.200903457
21. Claus C. Neue Beitrage zur Chemie der Platinmetalle. Uber das Ruthenium verglichen mit dem ihm ahnlichen Osmium. Bull. Acad. Sci. St. Peterburg. 1861;5:87-129.
22. Bertini I., Gray G., Stifel E., Valentine J. Biologicheskaya neorganicheskaya khimiya: struktura i reaktsionnaya sposobnost’ (Biological inorganic chemistry: structure and reactivity): in 2 v. trans. from English. Moscow: Binom. Laboratoriya znanii, 2013. V. 1. 456 p. (in Russ.).
23. Nazarov A.A., Nosova Yu.N., Milaeva E.R. Compounds of ruthenium with biologically active ligands are effective antiproliferative agents. In collection: Mezhdistsiplinarnyi simpozium po meditsinskoi, organicheskoi i biologicheskoi khimii (Interdisciplinary Symposium on Medical, Organic and Biological Chemistry), 2015. P. 55. (in Russ.).
24. Nazarov A.A., Nosova Yu.N., Mikhalev O.V., Kovaleva O.N., Dyson P.J., Milaeva E.R. Antiproliferative activity of ruthenium and osmium clusters with phosphine ligands. Russ. Chem. Bull. 2016;65(2):546-549. http://dx.doi.org/10.1007/s11172-016-1335-x
25. Tfouni E., Krieger M., McGarvey B.R., Franco D.W. Structure, chemical and photochemical reactivity and biological activity of some ruthenium amine nitrosyl complexes. Coord. Chem. Rev. 2003;236(1-2):57-69. https:// doi.org/10.1016/S0010-8545(02)00177-7
26. Nazarov A., Mendoza Ferri Maria Grazia, Hanif M., Keppler B.K., Dyson P.J., Hartinger C.G. Understanding the interactions of diruthenium anticancer agents with amino acids. J. Biol. Inorg. Chemi. 2018;23(7):1159-1164. http://dx.doi.org/10.1007/s00775-018-1597-x
Supplementary files
|
1. Fig. 2. Ruthenium Market Overview 2014–2018 (2019 – forecast) | |
Subject | ||
Type | Исследовательские инструменты | |
View
(9KB)
|
Indexing metadata |
Review
For citations:
Buslaeva T.M., Fesik E.V., Khan N.A. Ruthenium: Past and Present. Fine Chemical Technologies. 2019;14(6):22-30. https://doi.org/10.32362/2410-6593-2019-14-6-22-30