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Formylation of metallocomplexes of p- and m-tetraanizylporphyrins

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Abstract

The Vilsmeyer formylation reaction a of metallocomplexes of m- and p- methoxy-substituted tetraphenylporphyrins was investigated. Formyl derivatives of m-isomers were shown to form cyclization products not only in solutions but in solid state. Ability to such transformations decreases in a number Co>Cu>Ni>Pd>Pt.

About the Authors

S. V. Tsukanov
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation


V. D. Rumyantseva
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation


A. F. Mironov
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation


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For citation:


Tsukanov S.V., Rumyantseva V.D., Mironov A.F. Formylation of metallocomplexes of p- and m-tetraanizylporphyrins. Fine Chemical Technologies. 2006;1(4):71-75. (In Russ.)

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ISSN 2410-6593 (Print)
ISSN 2686-7575 (Online)