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Pheophorbide a effect upon dark- and photooxidation of olefins

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Abstract

Peculiarities of pheophorbide’s a behavior in conditions of photosensitized and dark oxidation of natural olefin limonene have been analyzed. It is shown that phaeophorbide a is the photosensitizer of limonene oxidation, but it does not act upon its dark oxidation and it does not interreact with peroxides. Although pheophorbide is spent in reactions with radicals formed under H2O2 catalyzed decomposition, and it forms complexes with compounds including zinc and cobalt

About the Authors

O. V. Kradenova
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation


D. A. Krugovov
ИХФ им. Н.Н. Семенова РАН
Russian Federation


E. A. Larkina
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation


E. P. Tkachevskaya
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation


O. T. Kasaikina
ИХФ им. Н.Н. Семенова РАН
Russian Federation


References

1. А.Ф. Миронов. //Соросовский образовательный журнал.– 1996. – №8. – С. 32-40.

2. А.Ф. Миронов. //Итоги науки и техники. Современные проблемы лазерной

3. физики. – 1990. – Т.3. – С. 5-61.

4. Г.М. Кузнецова, Т.В.Лобанова, И.Ф.Русина, О.Т.Касаикина. //Изв. РАН, Сер.хим.

5. – 1996 – №7. – С.1676-1681.

6. Л.М.Писаренко, В.Г.Кондратович, О.Т. Касаикина. //Изв. РАН, Сер. хим. – 2004.

7. – №10. – С. 2110-2123.

8. E.N. Frankel. Lipid oxidation. /The Oily Press, Dundee (Scotland) – 1998. – 303 р.

9. C.S.Foot. //W.A.Pryor, Ed. v.2. N. Y: Academic Press. – 1976. – P.85.

10. O.T.Kasaikina, V.V.Vedutenko, A.M.Kashkay, V.D.Kortenska, M.I.Boneva,

11. N.V.Yanishlieva. //Oxid. Comm. – 2002. – Vol. 25, № 2. – P.232-243.

12. Н.М.Эмануэль, Е.Т.Денисов, З.К.Майзус. Цепные реакции окисления

13. углеводородов в жидкой фазе. – М.: Наука, 1965 – 375 с.

14. Emanuel, D. Gal: Modelling of Oxidation Processes, Prototype: The Oxidation of

15. Ethylbenzene. – Budapest: Akademiai Kiado, 1986. – 107 р.

16. А.А.Вайсберг, Д.Проскауэр, Дж.Риддик, Э.Тупс. Органические растворители. –

17. М.: Изд-во. иностр. лит., 1958. – С.154.

18. A.S.Brandis, A.N.Kozyrev, A.F.Mironov. //Tetrahedron. – 1992.– Vol. 48. – P. 6491-

19.


For citation:


Kradenova O.V., Krugovov D.A., Larkina E.A., Tkachevskaya E.P., Kasaikina O.T. Pheophorbide a effect upon dark- and photooxidation of olefins. Fine Chemical Technologies. 2006;1(4):44-49. (In Russ.)

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