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Methods of synthesis of metallaboranes with polyhedral cage [MB9H9], M=Ni, Pd

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Abstract

A new method of synthesis of polyhedral metallaboranes [ MB9 H9 ] ( M = Ni , Pd ) with an apical metal atom was suggested . The method consists in a reaction between ((C6H5)4P)2[B9H9] and different metal complexes of Ni(I), Ni(II) and Pd(II) both in organic solutions and in solid state with mechanical activation. The obtained metallaboranes were described with IR, NMR spectral data and elemental analysis.

About the Authors

A. Yu. Bykov
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation


N. A. Selivanov
Институт общей и неорганической химии им. Н.С. Курнакова РАН
Russian Federation


N. A. Votinova
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation


N. B. Generalova
Институт общей и неорганической химии им. Н.С. Курнакова РАН
Russian Federation


K. Yu. Zhizhin
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation


N. T. Kuznetsov
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation


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For citation:


Bykov A.Yu., Selivanov N.A., Votinova N.A., Generalova N.B., Zhizhin K.Yu., Kuznetsov N.T. Methods of synthesis of metallaboranes with polyhedral cage [MB9H9], M=Ni, Pd. Fine Chemical Technologies. 2012;7(6):64-68. (In Russ.)

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