chemicallytechFine Chemical TechnologiesТонкие химические технологии2410-65932686-7575MIREA – Russian Technological University (RTU MIREA).chemicallytech-677Research ArticleCHEMISTRY AND TECHNOLOGY OF INORGANIC MATERIALSХИМИЯ И ТЕХНОЛОГИЯ НЕОРГАНИЧЕСКИХ МАТЕРИАЛОВMethods of synthesis of metallaboranes with polyhedral cage [MB9H9], M=Ni, PdМетоды синтеза металлаборанов с полиэдрическим остовом [MB9H9], где M = Ni, PdБыковА. Ю.BykovA. Yu.bykov@igic.ras.ruСеливановН. А.SelivanovN. A.noemail@neicon.ruВотиноваН. А.VotinovaN. A.noemail@neicon.ruГенераловаН. Б.GeneralovaN. B.noemail@neicon.ruЖижинК. Ю.ZhizhinK. Yu.noemail@neicon.ruКузнецовН. Т.KuznetsovN. T.noemail@neicon.ruМИТХТ им. М.В. Ломоносова, 119571, Москва, пр-т Вернадского, д. 86РоссияM.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571Russian FederationИнститут общей и неорганической химии им. Н.С. Курнакова РАНRussian Federation201228122012766468Copyright © Bykov A.Y., Selivanov N.A., Votinova N.A., Generalova N.B., Zhizhin K.Y., Kuznetsov N.T., 20122012Быков А.Ю., Селиванов Н.А., Вотинова Н.А., Генералова Н.Б., Жижин К.Ю., Кузнецов Н.Т.Bykov A.Y., Selivanov N.A., Votinova N.A., Generalova N.B., Zhizhin K.Y., Kuznetsov N.T.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.finechem-mirea.ru/jour/article/view/677

A new method of synthesis of polyhedral metallaboranes [ MB9 H9 ] ( M = Ni , Pd ) with an apical metal atom was suggested . The method consists in a reaction between ((C6H5)4P)2[B9H9] and different metal complexes of Ni(I), Ni(II) and Pd(II) both in organic solutions and in solid state with mechanical activation. The obtained metallaboranes were described with IR, NMR spectral data and elemental analysis.

Предложен новый способ получения полиэдрических десятивершинных металлаборанов [ MB9 H9 ] ( M = Ni , Pd ) с атомом металла в апикальной позиции. В основе метода лежит взаимодействие (( C6 H5 )4 P )2[ B9 H9 ] с различными координационными соединениями Ni ( I ), Ni ( II ) и Pd ( II ) как в среде органических растворителей, так и твердофазное при механической активации. Полученные металлабораны охарактеризованы методами ИК, ЯМР спектроскопии, элементным анализом.

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The authors declare that there are no conflicts of interest present.