The synthesis of high dispersed polstyrene suspensions with narrow particle distribution by sizes
Abstract
Polysterene suspensions with particle diameters of 0.05-0.2 microns and narrow distribution by sizes can be synthesized at polymerization of styrene in high-disperse emulsions at high temperature and low concentration of monomer in the presence of ionic surfactant. Monodisperse polymeric suspensions with a diameter of particles 0.2 microns were prepared only in the presence of water-soluble inhibitor.
About the Authors
D. B. Adikanova
Satbayev Kazakh National Technical University
Kazakhstan
Kazakhstan
G. Zh. Eligbaeva
Satbayev Kazakh National Technical University
Kazakhstan
Kazakhstan
E. V. Milushkova
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation
Russian Federation
I. А. Gritskova
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation
Russian Federation
N. A. Lobanova
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation
Russian Federation
N. I. Prokopov
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation
Russian Federation
S. M. Levachev
M.V. Lomonosov Moscow State University, Moscow, 119991
Russian Federation
Russian Federation
A. E. Harlov
M.V. Lomonosov Moscow State University, Moscow, 119991
Russian Federation
Russian Federation
M. Haddazh
Peoples’ Friendship University of Russia, Moscow, 117198
Russian Federation
Russian Federation
References
1. Hansen F.K., Ugelstad J. Particle formation mechanisms / In: Emulsion Polymerization / Ed. I. Piirma. NY: Academic Press, 1982. Р. 51-91.
2. Елисеева В.И. Новая теория эмульсионной полимеризации. Получение латексов и их модификация. М.: Химия, 1977. С. 3-9.
3. Елисеева В.И., Иванчев С.С., Кучанов С.И., Лебедев А.В. Эмульсионная полимеризация и ее применение в промышленности. М.: Химия, 1976. 249 c.
4. Fitch R.M., Tsai C.H. Homogeneous nucleation of polymer colloids. IV. The role of soluble oligomeric radicals / In : Polymer Colloids. NY: Plenum Press, 1971. P. 103-116.
5. Adamson A.W. Physical Chemistry of Surface. NY: J. Wileyand Sons. Inc., 1990. 280 р.
6. Gilbert R.G. Emulsion Polymerization: A Mechanistic Approach. London: Academic Press, 1995. 362 р.
7. Fitch R.M. Polymer Colloids: A Comprehensive Introduction. London: Academic Press, 1997. 343 р.
8. Khomikovskij P.M. // Uspekhi khimii (Russian Chemical Reviews). 1958. T. 27. Is. 2. P. 1025-1055. (in Russ.).
9. Khomikovskij P.M. // Uspekhi khimii (Russian Chemical Reviews). 1959. T. 28. Is. 5. P. 547-575. (in Russ.).
10. Pepard B. Particle nucleation phenomena in emulsion polymerization of polystyrene: Retrospective theses and dissertations. Iowa State University. University Microfilms, Ann Arbor, 1974. 62 р.
11. Tauer K., Kuhn I. // Macromolecules. 1996. V. 28. P. 2236-2239.
12. Грицкова И.А. Эмульсионная полимериза- ция малорастворимых в воде мономеров: автореф. дис. … д-ра хим. наук. М.: МИТХТ, 1978. 24 с.
13. Huie R., Cherry W.R. // J. Org. Chem. 1985. V. 50. № 9. Р. 1531-1532.
14. Жаченков С.В. Влияние дисперсного состава эмульсий на кинетические закономерности полимеризации мало растворимых в воде мономеров: авто- реф. дис. … д-ра хим. наук. М.: МИТХТ, 2013. 46 с.
15. Хаддаж М. Образование частиц при радикальной гетерофазной полимеризации стирола: авто- реф. дис. … д-ра хим. наук. М.: МИТХТ, 2011. 47 с.
For citation:
Adikanova D.B., Eligbaeva G.Zh., Milushkova E.V., Gritskova I.А., Lobanova N.A., Prokopov N.I., Levachev S.M., Harlov A.E., Haddazh M. The synthesis of high dispersed polstyrene suspensions with narrow particle distribution by sizes. Fine Chemical Technologies. 2015;10(2):71-77. (In Russ.)
Views: 126
Email this article 