Палладий-катализируемое аллилирование норборнадиена: Экспериментальные и квантово-химические исследования

Цели. Каталитические процессы с участием норборнадиена (НБД) и производных норборненового (НБН) ряда открывают исключительные возможности для синтеза широкого круга карбоциклических углеводородов. Значительное расширение их ассортимента позволяет впоследствии получать материалы с широким спектром прогнозируемых свойств. Целью обзора является обобщение последних достижений в области создания новых процессов, катализируемых соединениями палладия. Значительное внимание уделено исследованию механизмов группы реакций аллилирования НБД совокупностью экспериментальных и теоретических методов.

Результаты. Рассмотрены различные стратегии молекулярного дизайна палладиевых катализаторов для синтезов на основе НБН и НБД. Показана возможность реализации различных направлений аллилирования НБД. Обсуждены факторы, влияющие на направление реакций и позволяющие селективно получать индивидуальные продукты.

Выводы. Разработка новых каталитических процессов с участием НБД и НБН-производных требует комплексного применения синтетических, кинетических, изотопных и квантово-химических подходов. Совокупность инструментальных и теоретических методов, имеющих обратные связи, позволяет оптимизировать поиск оригинальных каталитических систем, получать информацию о механизмах их действия и направленно влиять на технологические параметры.

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