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Model of the transition of polymer to a mesophase state

Abstract

Abstract- it was shown that the structural instability of a polymer crystal can be related to trapping different types of lattice vibrations in nonlinear resonances. The trapping condition is the excess of intramode anhar - monicity over intermode interaction. A model of the transition in polymer type polymetil-metacrilat was constructed. It is shown that a coherent state of orientational vibrations of heavy atomic groups are formed below the transition point.  It was established that the structural instability of the polymer crystal is the second- order phase transitions.

For citations:


Zabelina A.A., Savin E.S. Model of the transition of polymer to a mesophase state. Fine Chemical Technologies. 2006;1(3):75-80.

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ISSN 2410-6593 (Print)
ISSN 2686-7575 (Online)