New oscillating reaction – phenylacetylene oxidative carbonylation to anhydride of phenylmaleic acid
Abstract
In area of the catalytic reactions with metal complexes new oscillatory process - reaction of phenylacetylene oxidative carbonylation to anhydride of phenylmaleic acid in the system LiBr-PdBr2-CO-O2-(CH3)2CO is found. Independence of a oscillations mode of a gases mixture composition is shown at the percentage of CO no more than 50 %. The preliminary mechanism of process was proposed.
About the Authors
S. N. Gorodsky
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation
Russian Federation
O. V. Kasatkina
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation
Russian Federation
L. G. Bruk
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation
Russian Federation
O. N. Temkin
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation
Russian Federation
References
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2. M. M. Slinko, N. Jaeger, Oscillating Heterogeneous Catalytic Systems, Elsevier, Studies in Surface Science and Catalysis, 1994, v. 86, pp. 1- 408.
3. О. Н. Темкин, Л. Г. Брук, Комплексы Pd(II, I, 0) в каталитических реакциях окислительного карбонилирования. Кинетика и катализ, 2003, т. 44, № 5, с. 661-676.
Review
For citations:
Gorodsky S.N., Kasatkina O.V., Bruk L.G., Temkin O.N. New oscillating reaction – phenylacetylene oxidative carbonylation to anhydride of phenylmaleic acid. Fine Chemical Technologies. 2006;1(2):73-76. (In Russ.)
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