Preview

Fine Chemical Technologies

Advanced search

New oscillating reaction – phenylacetylene oxidative carbonylation to anhydride of phenylmaleic acid

Full Text:

Abstract

In area of the catalytic reactions with metal complexes new oscillatory process - reaction of phenylacetylene oxidative carbonylation to anhydride of phenylmaleic acid in the system LiBr-PdBr2-CO-O2-(CH3)2CO is found. Independence of a oscillations mode of a gases mixture composition is shown at the percentage of CO no more than 50 %. The preliminary mechanism of process was proposed.

About the Authors

S. N. Gorodsky
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation


O. V. Kasatkina
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation


L. G. Bruk
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation


O. N. Temkin
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation


References

1. Колебания и бегущие волны в химических системах, под ред. Р. Филда и М. Бургер, М., Мир, 1988.

2. M. M. Slinko, N. Jaeger, Oscillating Heterogeneous Catalytic Systems, Elsevier, Studies in Surface Science and Catalysis, 1994, v. 86, pp. 1- 408.

3. О. Н. Темкин, Л. Г. Брук, Комплексы Pd(II, I, 0) в каталитических реакциях окислительного карбонилирования. Кинетика и катализ, 2003, т. 44, № 5, с. 661-676.


For citation:


Gorodsky S.N., Kasatkina O.V., Bruk L.G., Temkin O.N. New oscillating reaction – phenylacetylene oxidative carbonylation to anhydride of phenylmaleic acid Fine Chemical Technologies. 2006;1(2):73-76. (In Russ.)

Views: 59


ISSN 2410-6593 (Print)
ISSN 2686-7575 (Online)