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Synthesis new substances of norbornene`s series toward photochemical energy storage

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Abstract

Modification of norbornadien (NBD) for using as solar energy storage was attempted. Synthesed adducts was investigated in the reaction of catalytic allylation by Pd<sub>3</sub>(OAc)<sub>6</sub> – PPh<sub>3</sub> and Ni(C<sub>3</sub>H<sub>5</sub>)<sub>2</sub> – P(i-C<sub>3</sub>H<sub>7</sub>O)<sub>3</sub> complexes and reaction parametres were optimized. Supramolecular substances, combinated NBD and 4-oxoretinal or 5,6-dioxo-5,6-sekoretinal, were suggested toward photochemical energy storage and optical memory systems by means of the photochromic valence isomerization of the NBD – quadricyclane system.

About the Authors

S. V. Leont`eva
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation


V. R. Flid
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation


References

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For citation:


Leont`eva S.V., Flid V.R. Synthesis new substances of norbornene`s series toward photochemical energy storage. Fine Chemical Technologies. 2007;2(2):78-81. (In Russ.)

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ISSN 2410-6593 (Print)
ISSN 2686-7575 (Online)