Properties of rhenium, nickel, cobalt alkoxides and their decomposition products
Abstract
New technology to obtain Re, Ni, Co hydroxides, simple and complex oxides, fine and nanosized powders of metals and alloys has been developed. Mono- and heterometallic nickel, rhenium and cobalt alkoxides with adjustable metal content were used as precursors to produce final powders.
About the Authors
I. V. Mazilin
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation
Department of Rare and Dispersed Elements, post-graduate student
Russian Federation
Department of Rare and Dispersed Elements, post-graduate student
D. V. Drobot
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation
Department of Rare and Dispersed Elements, department chairman
Russian Federation
Department of Rare and Dispersed Elements, department chairman
References
1. Geddes B., Leon H., Huang X. Superalloys: Alloying and Performance. ASM International, 2010. P. 59–110.
2. Kablov E.N., Petrushin N.V., Sidorov V.V. Rhenium in nickel-base superalloys for single crystal gas turbine blades // In: Proc. 7th International Symposium on Technetium and Rhenium / Ed. K.E. German, B.F. Myasoedov, G.E. Kodina, A.Ya. Maruk, I. D. Troshkina. M.: Publishing House GRANITSA, 2011. P. 18–23.
3. Tuffias R.H., Kaplan R.B., Appel M.A. Rhenium and Rhenium alloys // In: Proc. Int. Symp. Orlando, Florida, USA, 10 – 14 Feb. 1997/ Ed. B.D. Bryskin. Publ. TMS. P. 275.
4. Turova N.Ya., Turevskaya E.P., Kessler V.G., Yanovskaya M.I. The Chemistry of Metal Alkoxides. Boston-Dordrecht-London: Kluwer Acad. Publ., 2002. 586 p.
5. Drobot D., Seisenbaeva G., Kessler V., Scheglov P., Nikonova O., Michnevich S., Petrakova O. Cluster and heterometallic alkoxide derivatives of rhenium and d-elements of V–VI groups // J. Cluster Sci. 2009. V. 20. P. 23–36.
6. Shcheglov P.A., Drobot D.V. Rhenium Alkoxides (Review) // Russ. Chem. Bull. 2005. V. 54. Р. 2247–2258.
7. Shcheglov P.A. Mono-, bi- and trimetallic rhenium oxoalkoxoderivatives (Synthesis, properties and application): PhD Thesis. M., 2002. 199 p.
8. Shcheglov P.A., Drobot D.V. Alkoxide Route to Re- and Mo–Based Metallic and Oxide Materials // Inorg. Mater. 2004. V. 40. Issue 2. Р. 176–183.
9. Shcheglov P.A., Drobot D.V., Seisenbaeva G.A., Gohil S., Kessler V.G. Alkoxide Route to Mixed Oxides of Rhenium, Niobium, and Tantalum: Preparation and X-ray Single-Crystal Study of a Novel Rhenium-Niobium Methoxo Complex, Nb2(OMe)8(ReO4)2 // Chem. Mater. 2002. V. 14. № 5. Р. 2378–2383.
10. Drobot D.V., Chernyshova O.V., Kriyzhovets O.S., Smirnova K.A., Mazilin I.V., Shevelkov A.V., Tsodikov M.V., Petrakova O.V., Chistyakov A.V. “Soft” chemistry methods appear as an effective way for production of superdispersive (nano-sized) materials based on Re and d-elements of V-VIII groups // In: Proc. 7th International Symposium on Technetium and Rhenium / Ed. K.E. German, B.F. Myasoedov, G.E. Kodina, A.Ya. Maruk, I.D. Troshkina. M.: Publishing House GRANITSA, 2011. Р. 44–52.
11. Flaschka H., Schwarzenbach G. Complexometric titrations. London: Methuen, 1969. Р. 244–248.
12. Baybaeva S., Krylova L. Methods for paint coatings analysis. M.: Chemistry, 1974. P. 324–326.
13. Hillebrad V.F., Lendel H.E., Bright G.A. A Practical Guide to Inorganic Chemical Analysis. M.: Chemistry, 1966. P. 372–381.
14. Rogova T.V., Turova N.Ya., Zhadanov B. V. About nickel alkoxides // Russ. J. Coord. Chem. 1985. V. 11. Р. 784–788.
15. Ermakov A.I., Belousov V.V., Drobot D.V., Shcheglov P.A. Electronic Structures and Properties of the Rhenium Alkoxo Derivatives // Russ. J. Coord. Chem. 2006. V. 32. № 10. Р. 701–706.
16. Nash A., Nash P. Nickel-Rhenium Binary Alloy Phase Diagram // Bull. of Alloy Phase Diagram. 1085. V. 6. Р. 348–350.
Review
For citations:
Mazilin I.V., Drobot D.V. Properties of rhenium, nickel, cobalt alkoxides and their decomposition products. Fine Chemical Technologies. 2013;8(3):29-33. (In Russ.)
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