MODIFICATION OF WATER POLYMER COMPOSITIONS FOR ELECTRODEPOSITION BY METALLOPORPHYRINS

It is known that coatings produced by electrodeposition, cured at high temperatures (180ºC and above).The aim of this study is reducing the energy intensity of production of polymer coatings, improving physical, mechanical properties of the polymer coatings and expansion of colors of paints for the electrodeposition. As the object of study was chosen lacquer KCh-0125, the main component of which is maleated polybutadiene. A micelle of film-forming neutralized tertiary amine is a colloidal particle size of 40 to 70 nm. One of the most effective and lowcost ways to the above problems is the introduction of the water-based oligomeric compositions hydrophobic modifiers. As modifiers were selected naturally occurring metalloporphyrins - cobalt (II) complex of pheophytin a (СоPh) and copper (II) complex of methylpheophorbide a (CuMPP). The method of introduction of the СоPh and the CuMPP of the water-based compositions for electrodeposition was developed. Colloid-chemical properties of the resulting compositions were studied. It was presented the most probable structure of the scheme colloidal particles modified by metalloporphyrins. It was conducted viscometric, spectral studies; the method of dynamic light scattering was used to determine the zeta potential and the size of colloidal particles. It was demonstrated high catalytic activity of metal complexes of porphyrins examined in structuring processes electrodeposited coatings when cured. Introduction of metalloporphyrins in the coating helps to reduce the curing temperature to 160°C. This makes it possible to reduce or duration, or a temperature curing coatings. The introduction of CuMPP make possible to obtain transparent coatings emerald green. Modified electrodeposited coatings also have good water and salt resistance.

electrodeposition, modification, metalloporphyrins, colloidal solution, colloidal particle, the properties of the solutions, the properties of the coatings

1. Koifman O.I., Ageeva T.A. Porfirinpolimery (Porphyrinpolymers). M.: Izd-vo Fiziko-matematicheskoj literatury, 2006. 194 p.

2. Bespalova G.N., Larin A.N. // Izvestiya vysshikh uchebnykh zavedeniy seriya «Khimiya i khimicheskaya tekhnologiya». 2008. V. 51. № 7. P. 50–52.

3. Tagirov A.R., Bespalova G.N., Larin A.N., Ageeva T.A., Lebedenko A.O. // Dizain. Materialy. Tekhnologiya (Design. Materials. Technology). 2012. № 5 (25). P. 30–33.

4. Nikolaeva O.I., Kurek S.S., Ageeva T.A., Koifman O.I. // Izvestiya vysshikh uchebnykh zavedeniy seriya «Khimiya i khimicheskaya tekhnologiya». 2004. V. 47. № 2. P. 146–149.

5. Tager A.A. Fiziko-khimiya polimerov (PhysicoChemistry of Polymers). M.: Nauchnyj mir, 2007. 576 p.