Development of synthesis of supported noble metal nanoparticles for preparation of catalysts used in portable hydrogen generators based on sodium borohydride hydrolysis
- Р Р‡.МессенРТвЂВВВВВВВВжер
- РћРТвЂВВВВВВВВнокласснРСвЂВВВВВВВВРєРСвЂВВВВВВВВ
- LiveJournal
- Telegram
- ВКонтакте
- РЎРєРѕРїРСвЂВВВВВВВВровать ссылку
Full Text:
Abstract
The reaction properties of supported rhodium nanoparticles depend on degree of interaction between rhodium chloride and support at the stage of preparation Rh/TiO2 catalysts. Their catalytic properties are defined by its calcinations temperature and presence of impurity on support surface
About the Authors
O. V. NetskinaRussian Federation
V. I. Simagina
Russian Federation
O. V. Komova
Russian Federation
References
1. Particle size effect in the catalytic hydrogenation of 2,4-dinitrotoluene over Pd/C catalysts / G. Neri [et al.] // Appl. Catal. A. - 2001. - Vol. 208. - P. 307-316.
2. Morphology and control of Pd nanoparticles / H. Choo [et al.] // J. Mol. Catal. A. - 2006. - Vol. 244. - P. 217-228.
3. Nanoimprinted electrodes for micro-fuel cell applications / A.D. Taylor [et al.] // J. Power Sources. - 2007. - Vol. 171. - P. 218-223.
4. Azad, A.-M. Development of ceria-supported sulfur tolerant nanocatalysts: Rh-based formulations / A.-M. Azad, M. J. Duran // Appl. Catal. A. - 2007. - Vol. 330. - P. 77-88.
5. Development of a 1 kW PEM fuel cell power source / T. Susai [et al.] // Fuel Cells Bulletin. - 2001. - Vol.3, №. 29. - P. 7-11.
6. Development of 10 kW-scale hydrogen generator using chemical hydride / Y. Kojima [et al.] // J. Power Sources. - 2004. - Vol. 125. - P. 22-26.
7. An ultrasafe hydrogen generator: aqueous, alkaline borohydride solutions and Ru catalyst / S. Amendola [et al.] // J. Power Sources. - 2000. - Vol. 85. - P. 186-189.
8. Millennium, Protonex demo fuel cartridge, deliver more P2 systems // Fuel Cells Bulletin. - 2007. - Vol.2007, № 2. - P. 7.
9. Pat. 6683025 SShA, MPK5 B01J21/00. Process for making a hydrogen generation catalyst / Amendola [et al.]. - № 09/999266 ; zayavleno 26.10.2001; opubl. 27.01.2004.
10. Dzis'ko, V. A. Osnovy metodov prigotovleniya katalizatorov / V. A. Dzis'ko. - Novosibirsk : Nauka, 1983. - 264 s.
11. Kraus, W. PowderCell for Windows/ Version 2.3. / W. Kraus, G. Nolze. - Berlin : Federal Institute for Materials Research and Testing, 1999.
12. Simagina, V. I. Vliyanie prirody aktivnogo komponenta i nositelya na aktivnost' katalizatorov gidroliza borgidrida natriya / V. I. Simagina, P. A. Storozhenko, O. V. Netskina, O. V. Komova, G. V. Odegova, T. Yu. Samoilenko, A. G. Gentsler // Kinetika i kataliz. - 2007. - T. 48, № 1. - S. 177-184.
13. Prokopchik, A. Yu. Kataliticheskoe razlozhenie BH4 - na Pt / A. Yu. Prokopchik, Ya. I. Val'syunene, I. I. Vinkyavichyus // Tr. AN Lit. SSR. - 1976. - T.93, № 2. - S. 3-11.
14. Prokopchik, A. Yu. Kataliticheskoe razlozhenie borgidrida na Rh / A. Yu. Prokopchik, Ya. I. Val'syunene // Tr. AN Lit. SSR. - 1974.- T.83, № 4. - S. 11-19.
15. Prokopchik, A. Yu. Kataliticheskoe razlozhenie BH4 - na Pd / A. Yu. Prokopchik, Ya. I. Val'syunene, A. S. Kashkyalis // Tr. AN Lit. SSR. - 1977. - T. 103, № 6. - S. 3-9.
16. Prokopchik, A. Yu. Kataliticheskoe razlozhenie BH4 - na Ru / A. Yu. Prokopchik, Ya. I. Val'syunene, A. Yu. Norgailaite // Tr. AN Lit. SSR. - 1974. - T. 84, № 5. - S. 17-24.
17. Hydrogen generation using sodium borohydride solution and metal catalyst coated on metal oxide / Y. Kojima [et al.] // Int. J. of Hydrogen Energy. - 2002. - Vol. 27. - P. 1029-1034.
18. Zhigach, A. F. Khimiya gidridov / A. F. Zhigach, D. S. Stasinevich. - L. : Khimiya, 1969. - 676 s.
19. Simagina, V. I. Vliyanie prirody aktivnogo komponenta i nositelya na aktivnost' katalizatorov gidroliza borgidrida natriya / V. I. Simagina, P. A. Storozhenko, O. V. Netskina, O. V. Komova, G. V. Odegova, T. Yu. Samoilenko, A. G. Gentsler // Kinetika i kataliz. - 2007. - T. 48, № 1. - S. 177 -184.
20. Simagina, V. I. Development of catalysts for hydrogen generation from hydride compounds / V. I. Simagina, P. A. Storozhenko, O. V. Netskina, O. V. Komova, G. V. Odegova, D. I. Kochubey // Catalysis: fundamental and application : III Intern. Conf., Novosibirsk, Russia. July 4 - 8. 2007. - Novosibirsk, 2007. - P. 111-112.
21. Hess, A. Surface acidity and catalytic behavior of modified zirconium and titanium dioxides / A. Hess, E. Kemnitz // Appl. Catal. A: General. - 1997. - Vol. 149. - P. 373-389.
22. Ivanov A.V. Issledovanie sistemy Pt/SO4/ZrO2 metodom IK-spektroskopii diffuznogo rasseyaniya / A.V. Ivanov, L.M. Kustov, T.V. Vasina, V.B. Kazanskii, P. Zoiten // Kinetika i kataliz. - 1997. - T. 38, № 3. - S. 438-445.
23. Stakheev, A. Yu. Effects of the support on the morphology and electronic properties of supported metal clusters: modern concepts and progress in 1990s / A. Yu. Stakheev, L. M. Kustov // Appl. Catal. A: General. - 1999. - Vol. 188. - P. 3-35.
Review
For citations:
Netskina O.V., Simagina V.I., Komova O.V. Development of synthesis of supported noble metal nanoparticles for preparation of catalysts used in portable hydrogen generators based on sodium borohydride hydrolysis. Fine Chemical Technologies. 2008;3(3):65-72.
Views:
318
ISSN 2410-6593 (Print)
ISSN 2686-7575 (Online)
ISSN 2686-7575 (Online)
Email this article 
