Measurement of interfacial tension in melts of polymer blends
Abstract
The apparatus construction and primary techniques used on measurements of surface and interfacial tensions in high-viscous polymer melts has been examined. This method is based on spinning drop theory by Vonnegut. Measured values of surface and interfacial tensions for several polymer systems show good correlation with corresponding data from literature. Relative error of the measurements was in the range of 2-8%
About the Authors
A. N. Matvienko
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation
Russian Federation
Yu. P. Miroshnikov
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation
Russian Federation
References
1. Полимерные смеси. /Ван Оуэн Х.. – М.: Мир, 1998. – Т. 1. – С.337-394.
2. Hobbs S.Y., Dekkers M.E.J., Watkins V.H. //Polymer. – 1988. – V.29. – P.1598-1602.
3. Пугачевич П.П., Бегляров Э.М., Лавыгин И.А.. Поверхностные явления в полимерах. – М.: Химия, 1982. – C.61-83.
4. Polymer Handbook. /Wu S. – N.Y.: Wiley, 1989. –P.VI/411-VI/434.
5. Полимерные смеси. /Ву С. – М.: Мир, 1981. – Т. 1. – С. 282-332.
6. Липатов Ю.С., Веселовский Д.Н., Керча Ю.Ю. и др. Справочник по физической химии полимеров. Свойства растворов и смесей полимеров. – Киев: Наукова думка, 1984. – С. 260-270.
7. Princen H.M., Zia I.Y.Z. //J. Colloid Interface Sci. – 1967. – V. 23, № 1. – P. 99-107.
8. Patterson T., Hut K.H., Grindstaff T.H. //J. Polym. Sci. – 1971. –V. 34, №10. – P. 31-43.
9. Elmendorp J. J., de Vos G. // Polym. Eng. Sci. – 1986. – V. 26, № 6. – P. 415-417.
10. Ван Кревелен Д.В. Свойства и химическое строение полимеров. – М.: Химия.1976. – 416 с.
11. Кей Дж., Лэби Т. Таблицы физических и химических постоянных. – М.: Государственное изд-во физико-математической литературы, 1962. – C.54-63.
For citation:
Matvienko A.N., Miroshnikov Yu.P. Measurement of interfacial tension in melts of polymer blends. Fine Chemical Technologies. 2006;1(5):69-74. (In Russ.)
Views: 45
Email this article 