Formylation of metallocomplexes of p- and m-tetraanizylporphyrins
Abstract
The Vilsmeyer formylation reaction a of metallocomplexes of m- and p- methoxy-substituted tetraphenylporphyrins was investigated. Formyl derivatives of m-isomers were shown to form cyclization products not only in solutions but in solid state. Ability to such transformations decreases in a number Co>Cu>Ni>Pd>Pt.
About the Authors
S. V. Tsukanov
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation
Russian Federation
V. D. Rumyantseva
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation
Russian Federation
A. F. Mironov
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation
Russian Federation
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Review
For citations:
Tsukanov S.V., Rumyantseva V.D., Mironov A.F. Formylation of metallocomplexes of p- and m-tetraanizylporphyrins. Fine Chemical Technologies. 2006;1(4):71-75. (In Russ.)
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