Synthesis and spectral characteristics of dyads based on tetraphenylporphyrin derivatives
Abstract
The dyads composed of 2-(2-carboxyvinyl)-5,10,20-tetraphenylporphyrin and zinc complex of 5-(p-aminophenyl)-10,15,20-triphenylporphyrin were synthesized and their spectral and photophysical properties were studied
About the Authors
N. V. Konovalova
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation
Russian Federation
E. V. Kirienko
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation
Russian Federation
V. N. Luzgina
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation
Russian Federation
References
1. Fukuzumi S. New perspective of electron transfer chemistry. Org. Biomol. Chem., 2003, V. 1, P. 609-620.
2. Gust D., Moore T.A., Moore A.L. Mimicking photosynthetic solar energy transduction. Acc. Chem. Res., 2001, V. 34, № 1, P. 40-48.
3. Osuka A., Tanabe N., Kawabata S., Yamazaki I., Nishimura Y. Synthesis and intramolecular electron- and energy-transfer reactions of polyyne- and polyene-bridged diporphyrins. J. Org. Chem., 1995, V. 60, № 22, P. 7177-7185.
4. Kawabata S., Yamazaki I., Nishimura Y., Osuka A. Singlet energy transfer in bis(phenylethynyl)phenylene-bridged zinc-free base hybrid diporphyrins. J. Chem. Soc., Perkin Trans. 2, 1997, № 3, P. 479-484.
5. Strachan J.-P., Gentemann S., Seth J., Kalsbeck W.A., Lindsey J.S., Holten D., Bocian D.F. Synthesis and characterization of tetrachlorodiarylethyne-linked porphyrin dimmers. Effect of linker architecture on intradimer electronic communication. Inorg. Chem., 1998, V. 37, № 6, P. 1191-1201.
6. Shinoda S., Tsukube H., Nishimura Y., Yamazaki I., Osuka A. Energy and electron transfer properties of methyl pheophorbide-a in zinc porphyrin- pheophorbide dyads. Tetrahedron, 1997, V. 53, № 40, P. 13657-13666.
7. Грибкова С.Е., Лузгина В.Н., Евстигнеева Р.П. Синтез производных тетрафенилпорфирина, ковалентно связанных с тирозином. Журн. орг. химии, 1993, Т. 29, № 4, С. 758-762.
8. Пономарев Г.В., Маравин Г.Б. Синтез и свойства 1-замещенных производных 5,10,15,20-тетрафенилпорфирина. Химия гетероцикл. Соединений, 1982, № 1. С. 59 – 64.
9. Гордон А., Форд Р. Спутник химика. М. Мир, 1976. С. 302.
10. Fungo F., Otero L.A., Sereno L., Silber J.J., Durantini E.N. Synthesis of porphyrin dyads with potential use in solar energy conversion. J. Mater. Chem., 2000, V. 10, P. 645-650.
11. Беллами Л. Инфракрасные спектры молекул. М. Изд-во иностранной литературы, 1957.
12. Anton J.A., Loach P.A. Transfer of excitation energy between porphyrin centers of a covalently linked dimmer. Photochem. Photobiol., 1987, № 28, P. 235-242.
13. Hsiao J.-S., Krneger B.P., Wagner R.W., Jonson T.E., Delaney J.K., Mauzerall D.C., Fleming G.R., Lindsey J.S., Bocian D.F., Donohoe R.J. Soluble synthetic multiporphyrin arrays. 2. Photodynamics of energy-transfer processes. J. Am. Chem. Soc., 1996, V. 118, № 45, P. 11181-11193.
Review
For citations:
Konovalova N.V., Kirienko E.V., Luzgina V.N. Synthesis and spectral characteristics of dyads based on tetraphenylporphyrin derivatives. Fine Chemical Technologies. 2006;1(1):38-43. (In Russ.)
Views: 126
Email this article 