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Heterobimetallic palladium-based carboxylates as a new way to mixed- metal nanomaterials

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Abstract

New synthetic approach to the preparation of palladium(II)-based heterobimetallic complexes was proposed. The complexes were prepared in high yields (85-95%) in single-crystalline form and structurally characterized by physicochemical methods, including X-ray structural analysis. All the complexes are built based on the structural motif [Pd(-OOCR)4M] (R = Me, tBu; M = Cu(II), Zn(II), Ni(II), Co(II), Mn(II), Ce(IV), Nd(III), Sm(III), Eu(III), Tm(III), Yb(III)). Reduction of the heterobimetallic complexes can produce new mixed-metal nanomaterials

About the Authors

N. Yu. Kozitsyna
Институт общей и неорганической химии им. Н. С. Курнакова РАН
Russian Federation


M. N. Vargaftik
Институт общей и неорганической химии им. Н. С. Курнакова РАН
Russian Federation


S. E. Nefedov
Институт общей и неорганической химии им. Н. С. Курнакова РАН
Russian Federation


I. A. Yakushev
Институт общей и неорганической химии им. Н. С. Курнакова РАН
Russian Federation


I. I. Moiseev
Институт общей и неорганической химии им. Н. С. Курнакова РАН
Russian Federation


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For citation:


Kozitsyna N.Yu., Vargaftik M.N., Nefedov S.E., Yakushev I.A., Moiseev I.I. Heterobimetallic palladium-based carboxylates as a new way to mixed- metal nanomaterials. Fine Chemical Technologies. 2007;2(3):10-21. (In Russ.)

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