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Chemiluminescent Reactions of Luminol and N-Octylluminol with a Hypochlorite in Non-ionic Surfactants

https://doi.org/10.32362/2410-6593-2019-14-3-90-97

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Abstract

The chemiluminescent reaction of luminol is widely used for analytical purposes. Surface-active components of biological membranes are often present in biochemical studies and in many real objects of analysis. Their influence on the chemiluminescent reaction of luminol has not been systematically studied. Therefore, it is necessary to investigate this chemiluminescent reaction in organized molecular systems - micellar, vesicular and other systems simulating biological membranes. Micellar medium may also provide an additional opportunity to control chemiluminescent reactions, primarily with the aim of increasing their efficiency. The kinetics of the chemiluminescent oxidation of luminol and its hydrophobic analogue N-octylluminol with a hypochlorite ion in aqueous solutions and micellar solutions of non-ionic surfactant Triton X-100 was studied in the present work. It was shown that the growth and fading of the luminol and N-octylluminol chemiluminescence is adequately described by a two-exponential dependence, and the effective rate of increase in the intensity of chemiluminescence is directly proportional to the concentration of the hypochlorite ion. The dependences of the rate of accumulation and consumption of the intermediate product on the presence and concentration of surfactants in the reaction mixture are determined. The results are discussed in terms of the effect of localization of the reagents and intermediate reaction products.

About the Authors

T. V. Yankova
MIREA - Russian Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)
Russian Federation

Tatyana V. Yankova - Head of the Specialized Educational Laboratory of Hydrogen Energy and Renewable Energy Sources of the Chair of Energy Technologies, Systems and Installations.

86, Vernadskogo pr., Moscow 119571



P. V. Melnikov
MIREA - Russian Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)
Russian Federation

Pavel V. Melnikov - Ph.D. (Physics and Mathematics), Associate Professor of the Ya.K. Syrkin Chair of Physical Chemistry.

86, Vernadskogo pr., Moscow 119571

Scopus Author ID 18042368100, ResearcherID D-9773-2014



N. A. Yashtulov
MIREA - Russian Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)
Russian Federation

Nikolay A. Yashtulov, D.Sc. (Chemistry), Professor of the Chair of Energy Technologies, Systems and Installations.

86, Vernadskogo pr., Moscow 119571

Scopus Author ID 6507694451



N. K. Zaitsev
MIREA - Russian Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)
Russian Federation

Nikolay K. Zaitsev - D.Sc. (Chemistry), Docent, Head of the Chair of Energy Technologies, Systems and Installations.

86, Vernadskogo pr., Moscow 119571

Scopus Author ID 57193485921



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Supplementary files

1. Fig. 2. The kinetic dependence modeled by the difference of two exponents and the experimental kinetic curve.
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Yankova T.V., Melnikov P.V., Yashtulov N.A., Zaitsev N.K. Chemiluminescent Reactions of Luminol and N-Octylluminol with a Hypochlorite in Non-ionic Surfactants. Fine Chemical Technologies. 2019;14(3):90-97. (In Russ.) https://doi.org/10.32362/2410-6593-2019-14-3-90-97

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