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ESTABLISHMENT OF ISOMERIC COMPOSITION OF INSECTICIDAL CYPERMETHRIN SUBSTANCE BY RP-HPLC

https://doi.org/10.32362/2410-6593-2017-12-1-76-82

Abstract

The determination of cypermethrin, one of the most sought pyrethroid insecticides having a wide range of activities, by isocratic RP-HPLC is considered. The analysis of substances (technical products) with different content of both the geometrical (cis-, trans-) and optical (zetacypermethrin and alfacypermethrin) isomers of cypermethrin was carried out. Information about the content of the most active forms of cis- allows evaluating the effectiveness of the biological substance based only on RP-HPLC data, which in turn can be a decisive factor in the of the substance assessment supplier / manufacturer or ready commercial products. The optimum concentration range for determining the geometric isomers of cypermethrin in the working solution is from 0.2 to 1.0 mg/ml. The substance detection limit in working solutions/washings is 0.005 mg/ml.

About the Authors

L. A. Nosikova
Moscow Technological University (Institute of Fine Chemical Technologies)
Russian Federation
Moscow,119571 Russia


A. N. Kochetov
CJCS «METTEM-Technology»
Russian Federation
Balashikha, Moscow region, 143900 Russia


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Review

For citations:


Nosikova L.A., Kochetov A.N. ESTABLISHMENT OF ISOMERIC COMPOSITION OF INSECTICIDAL CYPERMETHRIN SUBSTANCE BY RP-HPLC. Fine Chemical Technologies. 2017;12(1):76-82. (In Russ.) https://doi.org/10.32362/2410-6593-2017-12-1-76-82

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ISSN 2410-6593 (Print)
ISSN 2686-7575 (Online)