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Kinetics and mechanism of oxidative polymerization of 2-methylaniline

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Abstract

The kinetics of oxidative polymerization of 2-methylaniline in hydrochloric acid aqueous solution in the presence of ammonium peroxydisulfate as the oxidant was studied. The presence of autocatalysis was demonstrated, and the reaction mechanism was suggested. On the basis of the mechanism a kinetic model of oxidative polymerization of 2-methylaniline was built. The model is in satisfactory agreement with the experimental results.

About the Authors

Ya. O. Mezhuev
D.I. Mendeleyev University of Chemical Technology of Russia, Moscow, 125047
Russian Federation


Yu. V. Korshak
D.I. Mendeleyev University of Chemical Technology of Russia, Moscow, 125047
Russian Federation


I. S. Strakhov
D.I. Mendeleyev University of Chemical Technology of Russia, Moscow, 125047
Russian Federation


M. I. Shtilman
D.I. Mendeleyev University of Chemical Technology of Russia, Moscow, 125047
Russian Federation


T. A. Vagramyan
D.I. Mendeleyev University of Chemical Technology of Russia, Moscow, 125047
Russian Federation


References

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For citation:


Mezhuev Y.O., Korshak Yu.V., Strakhov I.S., Shtilman M.I., Vagramyan T.A. Kinetics and mechanism of oxidative polymerization of 2-methylaniline. Fine Chemical Technologies. 2013;8(6):73-77. (In Russ.)

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ISSN 2410-6593 (Print)
ISSN 2686-7575 (Online)