Preview

Fine Chemical Technologies

Advanced search

Production of carbon nanofibers from organic raw materials electrocracking gas

Full Text:

Abstract

The article presents the results of research on the preparation of carbon nanofibers from an acetylene-containing gas formed as a result of the disposal of liquid industrial organic waste in the electrocracking process. It is shown that the electrocracking gas can be used for the production of carbon nanofibers. By changing the conditions of the synthesis and modifying the original catalyst it is possible to influence the increase of the output of carbon nanofibers.

About the Authors

A. I. Nikolaev
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation


B. V. Peshnev
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation


References

1. Baker R.T.K., Barber M.A., Harris P.S. Nucleation and growth of carbon deposits from nickel catalized decomposition of acetylene // J. Catal. 1972. V. 26. P. 51–58.

2. Su M., Zheng B., Liu К. A scalable CVD method for synthesis of single-walled carbon nanotubes with high catalyst productivity // J. Chem. Phys. Lett. 2000. V. 322. P. 321–326.

3. Louis B., Gulino G., Vieira R., Amadou J., Dintzer T., Galvagno S., Centi G., Ledoux M., Phm-Huu C. High yield synthesis of multi-walled carbon nanotubes by catalytic decomposition of ethane over iron supported on alumina catalyst // Catalysis Today. 2005. V. 102. P. 23–28.

4. Li Q., Yan H., Zhang J., Liu Z. «Pulsed» CVD growth of single-walled carbon nanotubes // Carbon. 2003. V. 41. P. 2873–2884.

5. Couteau E., Hernadi K., Seo J., Tiеn-Nga L., Mikо C., Gaаl R., Foffо L. CVD synthesis of high-purity multiwalled carbon nanotubes using CaCO3 catalysts support for large-scale production // Chem. Phys. Lett. 2003. V. 378. P. 9–17.

6. Li W.Z., Wen J.B., Sennett M., Ren Z.F. Clean double-walled carbon nanotubes synthesis by CVD // Chem. Phys. Lett. 2003. V. 368. P. 299–306.

7. Tang S., Zhong Z., Xiong Z., Sun L., Liu L., Lin J., Shen Z. X., Tan K. L. Controlled growth of single-walled carbon nanotubes by catalytic decomposition of CH4 over Mo/Co/MgO catalysts // Chem. Phys. Lett. 2001. V. 350. P. 19–26.

8. Perez-Mendoza M. Influence of molybdenum on the chemical vapour deposition production of carbon nanotubes // Nanotechnology. 2005. V. 16. P. 224-226.

9. Bacsa R., Laurent C., Peigney A., Vaugien T., Flahaut E., Bacsa W., Rousset A. Solid-solution precursors for the large-scale synsethis of carbon nanotubes by catalytic chemical vapor deposition // Am. Ceram. Soc. 2002. V. 85. P. 2666–2669.

10. Herrera J.E., Balzano L., Borgna A., Alwarez W.E., Resasco D.E. Relationship between the structure/composition of Co-Mo catalysts and their ability to produce single-walled carbon nanotubes by CO disproportionation // J. Catal. 2001. V. 204. P. 129-131.

11. Herrera J.E., Resasco D.E. Role of Co-W interaction in the selective growth of single-walled carbon nanotubes from CO disproportionation // J. Phys. Chem. 2003. V. 107. P. 3738-3742.

12. Французов В.К., Николаев А.И., Пешнев Б.В., Мензелеева М.Ф., Теплицкая И.В. Изучение макрокинетических особенностей процесса образования волокнистого углерода в реакторе ссыпного типа // Хим. промышленность. 1997. № 9. С. 13–16.


For citation:


Nikolaev A.I., Peshnev B.V. Production of carbon nanofibers from organic raw materials electrocracking gas. Fine Chemical Technologies. 2013;8(6):17-19. (In Russ.)

Views: 54


ISSN 2410-6593 (Print)
ISSN 2686-7575 (Online)