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Aluminum oxynitrides doped with rare-earth and transition metal ions

https://doi.org/10.32362/2410-6593-2025-20-4-324-343

EDN: KEDCJH

Abstract

Objectives. The work set out to summarize the results of the studies of aluminum oxynitrides (AlONs) doped with rare earth (REM) and transition metals (TM) and to highlight the main effects of REM and TM dopants on the formation, phase composition, and optical properties of the AlON.

Results. The presented analysis of the literature data includes the results of our own studies of the AlON doped with REM and TM ions. The influence of REM and TM additives on the formation of AlON and its phase com position, as well as optical properties, was considered.

Conclusions. It is clearly shown that the doping with REM and TM ions enhances the formation of pure AlON phase via high-temperature synthesis from oxide and nitride. The oxynitride matrix exhibits reducing properties with respect to both REM and TM. Doping with the REM ions leads to the emergence of luminescent properties in the visible range, while doping with TM ions affects the band gap in AlON as a semiconductor. The solubility limits of all metals in the AlON matrix do not exceed 1–2 at. % vs Al. Concentration quenching of luminescence is observed at REM contents from 0.1 to 0.5 at. %.

About the Authors

Nailya S. Akhmadullina
A.A. Baikov Institute of Metallurgy and Material Science, Russian Academy of Sciences
Russian Federation

Nailya S. Akhmadullina, Cand. Sci. (Chem.), Senior Researcher, Laboratory of Physical and Chemical Analysis of the Ceramic Materials

Scopus Author ID 26432528700

ResearcherID M-7540-2018

49, Leninskii pr., Moscow, 119991


Competing Interests:

Authors declare no conflicts of interest



Aleksey V. Ishchenko
Ural Federal University
Russian Federation

Alexey V. Ishchenko, Cand. Sci. (Phys.-Math.), Associate Professor, Senior Researcher, Department of Experimental Physics

Scopus Author ID 57195266830

19, Mira pr., Yekaterinburg, 620062

 


Competing Interests:

Authors declare no conflicts of interest



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Akhmadullina N.S., Ishchenko A.V. Aluminum oxynitrides doped with rare-earth and transition metal ions. Fine Chemical Technologies. 2025;20(4):324-343. https://doi.org/10.32362/2410-6593-2025-20-4-324-343. EDN: KEDCJH

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