Synthesis of novel amphiphilic block-copolymers by means of ATRP
Abstract
By means of ATRP the amphiphilic block-copolymers of polyisobornylacrylate-polyacrilic acid were produced. Kinetics of polymerization was investigated. Synthesized samples of polymers were characterized with molecular weight and polydispersity.
About the Authors
Yu. О. Кirilina
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation
Russian Federation
W. Van Camp
Polymer Chemistry Research Group, Ghent University
Belgium
Belgium
I. V. Bakeeva
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation
Russian Federation
F. E. Du Prez
Polymer Chemistry Research Group, Ghent University
Belgium
Belgium
V. P. Zubov
M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571
Russian Federation
Russian Federation
References
1. Synthesis of poly(isobornyl acrylate) containing copolymers by atom transfer radical polymerization / B. Dervaux, W. Van Camp, L. Van Renterghem, F. E. Du Prez // J. Polym. Sci. Part A: Polym. Chem. – 2008. – Vol. 46. – P. 1649–1661.
2. Mori, H. New polymeric architectures with (meth)acrylic acid segments / H. Mori, A. H. E. Müller // Prog. Polym. Sci. – 2003. – Vol. 28. – P. 1403–1439.
3. First nitroxide-mediated controlled free-radical polymerization of acrylic acid / L. Couvreur, C. Lefay, J. Belleney, B. Charleux, O. Guerret, S. Magnet // Macromolecules. – 2003. – Vol. 36. – P. 8260–8267.
4. Living free-radical polymerization by reversible addition-fragmentation chain transfer: the RAFT process/ J. Chiefari, B. Y. K. Chong, F. Ercole, J. Krstina, J. Jeffery, T. P. T. Le, R. T. A. Mayadunne, G. F. Meijs, C. L. Moad, G. Moad, E. Rizzardo, S. H. Thang // Macromolecules. – 1998. – Vol. 31. – P. 5559–5562.
5. Patten, T. E. Atom transfer radical polymerization and the synthesis of polymeric materials / T. E. Patten, K. Matyjaszewski // Adv. Mater. – 1998. – Vol. 10. – P. 901–915.
6. First example of the atom transfer radical polymerization of an acidic monomer: direct synthesis of methacrylic acid copolymers in aqueous media / E. J. Ashford, V. Naldi, R. O’Dell, N. C. Billingham, S. P. Armes // Chem. Commun. – 1999. – Vol. 114 – P. 1285–1286.
7. Davis, K. A. Preparation of block copolymers of polystyrene and poly(t-butyl acrylate) of various molecular weights and architectures by atom transfer radical polymerization / K. A. Davis, B. Charleux, K. Matyjaszewski // J. Polym. Sci. Part A: Polym. Chem. – 2000. – Vol. 38. – P. 2274–2283.
8. Atom transfer polymerization of methyl methacrylate mediated by alkylpyridylmethanimine type ligands, copper(I) bromide, and alkyl halides in hydrocarbon solution / D. M. Haddleton, M. C. Crossman, B. H. Dana, D. J. Duncalf, A. M. Heming, D. Kukulj, A. Shooter. // Macromolecules. – 1999. – Vol. 32. – P. 2110–2119.
9. Van Camp, W. Atom transfer radical polymerization of 1-ethoxyethyl (meth) acrylate: facile route toward near-monodisperse poly((meth) acrylic acid) / W. Van Camp, F. E. Du Prez // Macromolecules. – 2004. – Vol. 37. – P. 6673–6675.
10. Polymerization of methyl methacrylate with the carbon tetrachloride/dichlorotris- (triphenylphosphine)ruthenium(II)/methylaluminum bis(2,6-di-tert-butylphenoxide) initiating system: possibility of living radical polymerization / M. Kato, M. Kamigaito, M. Savamoto, T. Higashimura // Macromolecules. – 1995. – Vol. 28. – P. 1721–1723.
11. Matyjaszewski, K. Atom transfer radical polymerization / K. Matyjaszewski, J. Xia // J. Chem. Rev. – 2001. – Vol. 101. – P. 2921–2990.
12. Haddleton, D. M. Atom transfer radical polymerization of methyl methacrylate initiated by alkyl bromide and 2-pyridinecarbaldehyde imine copper(I) complexes/ D. M. Haddleton, C. B. Jasieczek, M. J. Hannon, A.J. Shotter // Macromolecules. – 1997. – Vol. 30. – P. 2190–2193.
13. Controlled radical polymerization of methacrylic monomers in the presence of a bis(orthochelated) arylnickel(II) complex and different activated alkyl halides/ C. Granel, P. Dubois, R. Jerome, P. Teyssie // Macromolecules. – 1996. – Vol. 29. – P. 8576–8582.
14. Percec, V. "Living" radical polymerization of styrene initiated by arenesulfonyl chlorides and CuI(bpy)nCl / V. Percec, B. Barboiu // Macromolecules. – 1995. – Vol. 28. – P. 7970–7972.
15. Braunecker, W. A. Controlled/living radical polymerization: features, developments, and perspectives / W. A. Braunecker, K. Matyjaszewski // Prog. Polym. Sci. – 2007. – Vol. 32. – P. 93–147.
16. Block copolymers of vinyl ethers as thermo-responsive colloidal stabilizers of organic pigments in aqueous media / N. Bulychev, I. Arutunov, B. Verdonck, E.J.Goetals, F.E. Du Prez // Macromol. Chem. Phys. – 2004. – Vol. 205, № 18. – P. 2457–2463.
17. Application of thermo-responsive poly(methyl vinyl ether) containing copolymers in combination with ultrasonic treatment for pigment surface modification in pigment dispersions / N. Bulychev, O. Confortini, P. Kopold, K. Dirnberger, T. Schauer, F.E. Du Prez, V. Zubov, C.D. Eisenbach // Polymer. – 2007. – Vol. 48. – P. 2636–2643.
Review
For citations:
Кirilina Yu.О., Camp W.V., Bakeeva I.V., Du Prez F.E., Zubov V.P. Synthesis of novel amphiphilic block-copolymers by means of ATRP. Fine Chemical Technologies. 2008;3(4):32-38. (In Russ.)
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