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ACETONE-CHLOROFORM-n-BUTANOL MIXTURE SEPARATION BY THE EXTRACTIVE DISTILLATION IN SCHEMES OF TWO-OUTLET COLUMNS

https://doi.org/10.32362/2410-6593-2017-12-5-34-46

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About the Authors

E. А. Anokhina
Moscow Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)
Russian Federation

Ph.D. (Engineering), Associate Professor, Chair of Chemistry and Technology of General Organic Synthesis

86, Vernadskogo Pr., Moscow, 119571, Russia



I. M. Gracheva
Moscow Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)
Russian Federation

Student, Chair of Chemistry and Technology of General Organic Synthesis

86, Vernadskogo Pr., Moscow, 119571, Russia



A. Yu. Akishin
Moscow Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)
Russian Federation

Postgraduate Student, Chair of Chemistry and Technology of General Organic Synthesis

86, Vernadskogo Pr., Moscow, 119571, Russia



А. V. Timoshenko
Moscow Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)
Russian Federation

Dr.Sc. (Engineering), Professor, Chair of Chemistry and Technology of General Organic Synthesi

86, Vernadskogo Pr., Moscow, 119571, Russia



References

1. Timoshenko A.V., Anokhina E.A., Timofeev V.S. A way for separation of the acetone–chloroform azeotropic composition mixture by extractive distillation: Patent 2207896 Russian Federation. № 2002107039; appl. 21.03.2002; publ.10.07.2003. (in Russ.).

2. Lei Z.G., Zhou R.Q., Duan Z.T. Process improvement on separating C4 by extractive distillation // Chem. Eng. J. 2002. V.85. P. 379–386.

3. Hernández S. Analysis of energy-efficient complex distillation options to purify bioethanol // Chem. Eng. Technol. 2008. V. 31. № 4. P. 597–603.

4. Timoshenko A.V., Anokhina E.A., Ivanova L.V. Extractive distillation systems involving complex columns with partially coupled heat and material flows // Theor. Found. Chem. Eng. 2005. V. 39. № 5. P. 463–470.

5. Timoshenko A.V., Morgunov A.V., Anokhina E.A. Flowsheet synthesis for the extractive distillation of azeotropic mixtures in systems consisting of columns with partially coupled heat and material flows // Theor. Found. Chem. Eng. 2007. V. 41. № 6. P. 845–850.

6. Anokhina E.A., Dolmatov B.B., Timoshenko A.V. The energy efficiency of the extractive distillation acetone–chloroform mixture in a complex column with a side section // Khimicheskaya technologiya (Chemical Engineering). 2008. V. 9. № 8. P. 402–407. (in Russ.).

7. Anokhina E.A., Pankova I.A., Timoshenko A.V. Study on effectiveness of complex columns with side section for extractive distillation of acetone–methanol mixtures with different composition // Khimicheskaya promyshlennost' segodnya (Chemical Industry Today). 2009. №. 3. P. 44–49. (in Russ.).

8. Anokhina E.A., Rudakov D.G., Timoshenko A.V. Energy efficiency of the extractive distillation of the isobutyl alcohol–isobutyl acetate mixture depending on the feed composition// Khimicheskaya technologiya (Chemical Engineering). 2010. V. 11. № 9. P. 549–556. (in Russ.).

9. Anokhina E.A., Shleynikova E.L., Timoshenko A.V. Energy efficiency of complexes with partially coupled thermally and material flows for extractive distillation of methyl acetate – chloroform mixture depending on entrainer // Vestnik MITHT (Fine Chemical Technologies). 2013. V. 8. № 2. P. 18–25. (in Russ.).

10. Anokhina E.A., Timoshenko A.V. Criterion of the energy effectiveness of extractive distillation in the partially thermally coupled columns // Chem. Eng. Res. Des. 2015. V. 99. P. 165–175.

11. Ivanova L.V., Prokhorenkova N.M., Surkova E.A., Morgunov A.V., Timoshenko A.V., Timofeev V.S. Energy-saving technologies of autoextractive distillation of an acetone – chloroform – n-butanol – dimethylformamide mixture // Theor. Found. Chem. Eng. 2006. V. 40. № 6. P. 580–586.

12. Anokhina E.A., Timoshenko A.V., Rebrovskaya A.E. Energy-saving schemes of benzene–cyclohexane–toluene mixture extractive distillation with N-methylpyrrolidone. Part 2. Schemes including systems

13. with partially coupled thermal and material flows // Khimicheskaya promyshlennost' segodnya (Chemical Industry Today). 2015. № 3. P. 46–57. (in Russ.).

14. Timoshenko A.V., Anokhina E.А., Morgunov А.V., Rudakov D.G. Application of the partially thermally coupled distillation flowsheets for the extractive distillation of ternary azeotropic mixtures // Chem. Eng. Res. Des. 2015. V. 104. P. 139–155.

15. Pirog L.A. Evaluation of the entrainer effectiveness in the separation of non-ideal mixtures by extractive distillation: diss. … Ph.D. (Engineering). Moscow, 1987. 204 p. (in Russ.).

16. Serafimov L.A. Thermodynamic and topological analysis of heterogeneous equilibrium diagrams of multicomponent mixtures // Rus. J. Phys. Chem. 2002. V. 76. № 8. P. 1211–1224.

17. Benyounes H. Regularities of azeotropic mixtures separation in the presence of selective entrainers: diss. …Ph.D. (Engineering). Moscow, 2002. 185 p. (in Russ.).

18. Segura H., Mejia A., Reich R., Wisniak J., Loras S. Isobaric vapor–liquid equilibria and densities for the binary systems oxolane + ethyl 1,1-dimethylethyl ether, oxolane + 2-propanol and propan-2-one + trichloromethane // Phys. Chem. Liq. 2003. V. 41. № 3. P. 283–301.

19. Michalski H., Michalowski S., Serwinski M., Strumillo C. Vapor–liquid equilibria for system acetone – n-butanol // Zesz. Nauk. Politechn. Lodzk., Chem. 1961. № 36. P. 73–84.

20. Misheneva I.N., Smirnova V.V., Saraev B.A., Pavlov S.Yu. Vapor–liquid equilibrium in ketone–dimethylformamide systems // Promyshlennost’ sinteticheskogo kauchuka (Synthetic Rubber Industry). 1980. № 11. P. 2–3. (in Russ.).

21. Subba Rao V.B., Venkata Rao C. Isopiestic binary vapor–liquid equilibria system chloroform (1)–n-butanol (2) // Chem. Eng. Sci. 1962. V.17. №7. P. 574–576.

22. Ivanova L.V., Timoshenko A.V., Timofeev V.S. Synthesis of flowsheets for extractive distillation of azeotropic mixtures // Theor. Found. Chem. Eng. 2005. V. 3. № 1. P. 16–23.

23. Arifin S., Chein I.-L. Design and control of an isopropyl alcohol dehydration process via extractive distillation using dimethtyl sulfoxide as an entrainer // Ind. Eng. Chem. Res. 2008. V. 47. №. 3. P. 790–803.

24. Wang S.-J., Huang H.-P., Yu Ch.-Ch. Plantwide design of transesterification reactive disstillation to cogenerate ethyl acetate and n-butanol // Ind. Eng. Chem. Res. 2010. V. 49. P. 750–760.

25. Emhamed A.M., Czuczai B., Rev E., Lelkes Z. Analysis of extractive distillation with mathematical programming // Ind. Eng. Chem. Res. 2008. V. 47. P. 9983–9995.

26. Kossack S., Kraemer K., Gani R., Marquardt W. A systematic synthesis framework for extractive distillation processes // Chem. Eng. Res. Des. 2008. V. 86. P. 781–792.

27. Garcia-Herreros P., Gomez J.M., Gil I.D., Rodrigues G. Optimization of the design and operation of an extractive distillation system for the production of fuel grade ethanol using glycerol as entrainer // Ind. Eng. Chem. Res. 2011. V. 50. P. 3977–3985.

28. Kafarov V.V., Vetokhin V.N., Boyarinov A.I. Programming and computational methods in chemistry and chemical technology. Moscow: Nauka Publ., 1972. 488 p. (in Russ.).

29. De Figueirêdo M.F., Guedes B.P., de Araújo J.M.M., Vasconcelos L.G.S., Romildo Pereira Brito R.P. Optimal design of extractive distillation columns – A systematic procedure using a process simulator // Chem. Eng. Res. Des. 2011. V. 89. P. 341–346.

30. Kiss A.A., Suszwalak D. J.-P.C. Enhanced bioethanol dehydration by extractive and azeotropic distillation in dividing-wall columns // Sep. Purif. Tech. 2012. V. 86. P. 70–78.

31. Kiss A.A., Ignat R.M. Innovative single step bioethanol dehydration in an extractive dividing-wall column // Sep. Purif. Tech. 2012. V. 98. P. 290–297.

32. Ostrovskij G.M., Volin Yu.M., Ziyatdinov N.N. Methods of optimization of chemical-technological processes. Moscow: KDU Publ., 2008. 424 p. (in Russ.)


Review

For citations:


Anokhina E.А., Gracheva I.M., Akishin A.Yu., Timoshenko А.V. ACETONE-CHLOROFORM-n-BUTANOL MIXTURE SEPARATION BY THE EXTRACTIVE DISTILLATION IN SCHEMES OF TWO-OUTLET COLUMNS. Fine Chemical Technologies. 2017;12(5):34-46. (In Russ.) https://doi.org/10.32362/2410-6593-2017-12-5-34-46

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