chemicallytechFine Chemical TechnologiesТонкие химические технологии2410-65932686-7575MIREA – Russian Technological University (RTU MIREA).10.32362/2410-6593-2016-11-6-15-27chemicallytech-55Research ArticleTHEORETICAL BASIS OF CHEMICAL TECHNOLOGYТЕОРЕТИЧЕСКИЕ ОСНОВЫ ХИМИЧЕСКОЙ ТЕХНОЛОГИИMULTICOMPONENT SYSTEMS WITH THREE-PHASE SPLITTING REGIONМНОГОКОМПОНЕНТНЫЕ СИСТЕМЫ С ТРЕХФАЗНЫМ РАССЛАИВАНИЕМФролковаА. В.FrolkovaA. V.

доцент, Кафедра химии и технологии основного органического синтеза

Москва, 119571 Россия

Moscow, 119571 Russia

frolkova_nastya@mail.ruАкишинаА. А.AkishinaA. A.

аспирант, Кафедра химии и технологии основного органического синтеза

Москва, 119571 Россия

Moscow, 119571 Russia

noemail@neicon.ruФролковаА. К.FrolkovaA. K.

заведующий кафедрой, Кафедра химии и технологии основного органического синтеза

Москва, 119571 Россия

Moscow, 119571 Russia

noemail@neicon.ruМосковский технологический университет (Институт тонких химических технологий)РоссияMoscow Technological University (Institute of Fine Chemical Technologies)Russian Federation2016281220161161527Copyright © Frolkova A.V., Akishina A.A., Frolkova A.K., 20162016Фролкова А.В., Акишина А.А., Фролкова А.К.Frolkova A.V., Akishina A.A., Frolkova A.K.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.finechem-mirea.ru/jour/article/view/55

A review of scientific publications that describe systems with a three-phase splitting region is presented. Mechanisms of a three-phase splitting region formation are shown. All the suggested classifications of diagrams with a three-phase splitting region are presented. Methods for studying the evolution of a three-phase splitting region are described. Problems connected with the mathematical modeling of liquid - liquid - liquid equilibrium are considered. The ability of mixtures to form three-phase splitting regions and opportunities of separating such mixtures by special methods is analyzed. A list of known systems with three and more liquid phases is presented.

В работе представлен обзор научных публикаций, посвященных исследованию систем с трехфазным расслаиванием, образованных соединениями различных классов. Рассмотрены механизмы образования областей трехфазного расслаивания. Приведены примеры классификаций диаграмм расслаивания многокомпонентных систем и описаны подходы к исследованию эволюции области трехфазного расслаивания. Также уделено внимание проблемам моделирования равновесия жидкость-жидкость-жидкость и использованию свойства смеси образовывать области трехфазного расслаивания для разделения смесей экстракционными методами и методами, сочетающими ректификацию и расслаивание. Приведен список известных на сегодняшний день систем с тремя и более жидкими фазами.

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The authors declare that there are no conflicts of interest present.