chemicallytechFine Chemical TechnologiesТонкие химические технологии2410-65932686-7575MIREA – Russian Technological University (RTU MIREA).10.32362/2410-6593-2023-18-4-328-340chemicallytech-1989Research ArticleCHEMISTRY AND TECHNOLOGY OF ORGANIC SUBSTANCESХИМИЯ И ТЕХНОЛОГИЯ ОРГАНИЧЕСКИХ ВЕЩЕСТВAnalysis of phase trajectories for studying the operational evolution of catalytic systemsАнализ фазовых траекторий реакций в исследованиях эволюции функционирования каталитических системhttps://orcid.org/0000-0002-1881-7620ШмидтА. Ф.SchmidtA. F.

Шмидт Александр Федорович, д.х.н., профессор кафедры физической и коллоидной химии, ректор

664003, Россия, г. Иркутск, ул. К. Маркса, д. 1

Scopus Author ID 7403416777, ResearcherID M-1405-2013

Alexander F. Schmidt, Dr. Sci. (Chem.), Full Professor, Professor, Department of Physical and Colloid Chemistry,Rector

1, K. Marksa ul., Irkutsk, 664003

aschmidt@chem.isu.ruhttps://orcid.org/0000-0002-8434-6820КурохтинаА. А.KurokhtinaA. A.

Курохтина Анна Аркадьевна, к.х.н., доцент, кафедра физической и коллоидной химии

664003, г. Иркутск, ул. К. Маркса, д. 1

Scopus Author ID 25221794400, ResearcherID A-6571-2016

Anna A. Kurokhtina, Cand. Sci. (Chem.), Associate Professor, Department of Physical and Colloid Chemistry

1, K. Marksa ul., Irkutsk, 664003

kurokhtina@chem.isu.ruhttps://orcid.org/0000-0001-9747-5659ЛаринаЕ. В.LarinaE. V.

Ларина Елизавета Владимировна, к.х.н., научный сотрудник, Научно-исследовательский институтнефте- и углехимического синтеза

664003,  г. Иркутск, ул. К. Маркса, д. 1

Scopus Author ID 48761510800, ResearcherID H-2003-2016

Elizaveta V. Larina, Cand. Sci. (Chem.), Researcher, Institute of Oil and Coal Chemical Synthesis

1, K. Marksa ul., Irkutsk, 664003

tendu90@mail.ruhttps://orcid.org/0000-0001-9771-8403ЛагодаН. А.LagodaN. A.

Лагода Надежда Александровна, младший научный сотрудник, Научно-исследовательский институт нефтеи углехимического синтеза

664003,  г. Иркутск, ул. К. Маркса, д. 1

Scopus Author ID 57191614560, ResearcherID S-9020-2017

Nadezhda A. Lagoda, Junior Researcher, Institute of Oil and Coal Chemical Synthesis

1, K. Marksa ul., Irkutsk, 664003

nalagoda@yandex.ruИркутский государственный университет, химический факультетРоссияIrkutsk State UniversityRussian Federation202308102023184328340Copyright © Schmidt A.F., Kurokhtina A.A., Larina E.V., Lagoda N.A., 20232023Шмидт А.Ф., Курохтина А.А., Ларина Е.В., Лагода Н.А.Schmidt A.F., Kurokhtina A.A., Larina E.V., Lagoda N.A.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.finechem-mirea.ru/jour/article/view/1989Objectives

Objectives. To establish details of catalytic systems operation using the kinetic method with no needs for the differentiation of primary experimental kinetic data.

Methods

Methods. Analysis of the time patterns of differential selectivity and relative reactivity of substrates in parallel or competing reactions was used.

Results

Results. For various coupling reactions of aryl halides and nucleophiles, the possibility to obtain the data about the evolution of the catalytic systems and patterns of the changes of catalytically active species under dynamic transformations of several active and inactive catalyst forms was demonstrated.

Conclusions

Conclusions. The analysis of the evolution of differential selectivity and relative reactivity under competing or parallel reactions is the useful tool for discrimination between probable hypotheses of complex catalytic process operation.

Цели

Цели. Определение деталей механизмов функционирования каталитических систем с помощью кинетического метода, не требующего дифференцирования первичных экспериментальных кинетических данных.

Методы

Методы. Анализ закономерностей изменения дифференциальной селективности и относительной реакционной способности субстратов в параллельных и конкурирующих реакциях во времени.

Результаты

Результаты. На примерах различных реакций сочетания арилгалогенидов с нуклеофилами показана возможность получения данных об эволюции каталитических систем и закономерностях изменений природы каталитически активных соединений в условиях динамических превращений нескольких активных и неактивных форм катализатора.

Выводы

Выводы. Эволюционный анализ величин дифференциальной селективности и относительной реакционной способности в ходе конкурирующих или параллельных реакций является эффективным инструментом дискриминации гипотез механизмов сложных каталитических процессов. 

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The authors declare that there are no conflicts of interest present.