chemicallytechFine Chemical TechnologiesТонкие химические технологии2410-65932686-7575MIREA – Russian Technological University (RTU MIREA).10.32362/2410-6593-2020-15-5-54-62chemicallytech-1650Research ArticleCHEMISTRY AND TECHNOLOGY OF INORGANIC MATERIALSХИМИЯ И ТЕХНОЛОГИЯ НЕОРГАНИЧЕСКИХ МАТЕРИАЛОВDetermining the phase stability of luminescent materials based on the solid solutions of oxyorthosilicates (Lu1−xLnx)[(SiO4)0.5O0.5], where Ln = La−YbОпределение фазовой стабильности люминесцентных материалов на основе твердых растворов оксиортосиликатов (Lu1−xLnx)[(SiO4)0.5O0.5], где Ln = La–Ybhttps://orcid.org/0000-0002-7665-556XГетьманЕ. И.Get’manE. I.

Гетьман Евгений Иванович, доктор химических наук, профессор кафедры неорганической, органической и аналитической химии факультета химии, биологии и биотехнологий. Scopus Author ID 6602738183

Украина, 21021, Винница, ул. 600-летия, 21

Eugeni I. Get’man, Dr. of Sci. (Chemistry), Full Professor. Scopus Author ID 6602738183

21, vul. 600–richchia, Vinnytsia, 21021, Ukraine

ie.getman@donnu.edu.uahttps://orcid.org/0000-0002-7328-6674ОлексийЮ. А.OleksiiYu. A.

Олексий Юлия Анатольевна, магистрант, лаборант образовательно-научной лаборатории специальных методов исследования в аналитической химии факультета химии, биологии и биотехнологий

Украина, 21021, Винница, ул. 600-летия, 21

Yuliia A. Oleksii, Master Student, Laboratory Assistant of the Educational-Scientific Laboratory of Special Research Methods in Analytical Chemistry

21, vul. 600–richchia, Vinnytsia, 21021, Ukraine

oleksii.i@donnu.edu.uahttps://orcid.org/0000-0001-9808-0392РадиоС. В.RadioS. V.

Радио Сергей Викторович, кандидат химических наук, заведующий научно-исследовательской частью, доцент кафедры неорганической, органической и аналитической химии факультета химии, биологии и биотехнологий. Scopus Author ID 12765904800, ResearcherID P-9022-2017

Украина, 21021, Винница, ул. 600-летия, 21

Serhii V. Radio, Cand. of Sci. (Chemistry), Head of the Department for Research, Associate Professor. Scopus Author ID 12765904800, ResearcherID P-9022-2017

21, vul. 600–richchia, Vinnytsia, 21021, Ukraine

radio@donnu.edu.uahttps://orcid.org/0000-0002-8562-3113АрдановаЛ. И.ArdanovaL. I.

Арданова Людмила Ивановна, профессор кафедры химии и геологии. Scopus Author ID 7801510561

США, 56001, Миннесота, Манкейто, Форд Холл, 241

Lyudmyla I. Ardanova, Associate Professor. Scopus Author ID 7801510561

241 Ford Hall, Mankato, Minnesota, 56001, USA

lyudmyla.stackpool@mnsu.eduДонецкий национальный университет им. Васыля СтусаУкраинаDepartment of Inorganic, Organic, and Analytical Chemistry, Faculty of Chemistry, Biology, and Biotechnologies, Vasyl’ Stus Donetsk National UniversityUkraineГосударственный университет МиннесотыСоединённые Штаты АмерикиDepartment of Biochemistry, Chemistry, and Geology, Minnesota State UniversityUnited States2020141120201555462Copyright © Get’man E.I., Oleksii Y.A., Radio S.V., Ardanova L.I., 20202020Гетьман Е.И., Олексий Ю.А., Радио С.В., Арданова Л.И.Get’man E.I., Oleksii Y.A., Radio S.V., Ardanova L.I.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.finechem-mirea.ru/jour/article/view/1650Objectives

Objectives. This study aimed to predict the limits of substitution and stability of luminescent materials based on low-temperature modifications of solid solutions (spatial group P21/c) with lutetium oxyorthosilicates (Lu1−xLnx)[(SiO4)0.5O0.5], where Ln represents the rare-earth elements (REEs) of the La–Yb series.

Methods

Methods. The V.S. Urusov’s crystal energy theory of isomorphous substitutions and a crystallochemical approach in the regular solid solution approximation were used to calculate the energies of the mixing (interaction parameters) of the solid solutions.

Results

Results. Using the V.S. Urusov’s theory, we calculated the energies of mixing (interaction parameters) in the systems under study. The dependences of the decomposition temperatures of solid solutions on the REE number and composition (x) were obtained and used to create a diagram of the thermodynamic stability of the solid solutions, allowing us to predict the substitution limits depending on the temperature or determine the decomposition temperature using the given substitution limits.

Conclusions

Conclusions. The results of the study can be useful when choosing the ratio of components in matrices (host materials) and the amount of the activator (dopant) in the new luminescent, laser, and other materials based on low-temperature modifications of solid solutions of “mixed” REE oxyorthosilicates (Lu1−xLnx)[(SiO4)0.5O0.5].

Цели

Цели. Целью работы явилось прогнозирование пределов замещения и стабильности люминесцентных материалов на основе низкотемпературных модификаций твердых растворов (пространственная группа Р21/с) на основе оксиортосиликата лютеция (Lu1−xLnx)[(SiO4)0.5O0.5], где Ln – редкоземельный элемент серии La–Yb.

Методы

Методы. Для расчета энергий смешения (параметров взаимодействия) для твердых растворов была использована теория изоморфной смесимости В.С. Урусова и кристаллохимический подход в приближении регулярного твердого раствора.

Результаты

Результаты. Получены зависимости температур распада твердых растворов от порядкового номера редкоземельных элементов и состава, которые использованы для построения диаграмм термодинамической устойчивости твердых растворов, что позволило прогнозировать пределы замещения в зависимости от температуры или определять температуру распада на основе заданных пределов замещения.

Выводы

Выводы. Результаты исследования могут быть полезны при выборе соотношения компонентов в матрице («хозяине») и количества активатора (допанта) в новых люминесцентных, лазерных и других материалах на основе низкотемпературных модификаций твердых растворов «смешанных» оксиортосиликатов редкоземельных элементов (Lu1−xLnx)[(SiO4)0.5O0.5].

оксиортосиликатредкоземельные элементыизоморфное замещениетвердый растворэнергия смешенияoxyorthosilicaterare-earth elementsisomorphous substitutionsolid solutionenergy of mixingИсследование выполнено в рамках Программы фундаментальных исследований Министерства образования и науки Украины (проекты №№ 0119U100025 и 0120U102059).This study was supported by the Fundamental Research Program funded by the Ministry of Education and Science of Ukraine (Projects Nos. 0119U100025 and 0120U102059); this article has been edited for English language and spelling by Enago, an editing brand of Crimson Interactive Inc.ReferencesWang J., Tian S., Li G., Liao F., Jing X. Preparation and X-ray characterization of low-temperature phases of R2SiO5 (R = rare earth elements). Mater. Res. Bull. 2001;36(10):1855-1861. https://doi.org/10.1016/S0025-5408(01)00664-XWang J., Tian S., Li G., Liao F., Jing X. Preparation and X-ray characterization of low-temperature phases of R2SiO5 (R = rare earth elements). 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The authors declare that there are no conflicts of interest present.