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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="en"><front><journal-meta><journal-id journal-id-type="publisher-id">chemicallytech</journal-id><journal-title-group><journal-title xml:lang="en">Fine Chemical Technologies</journal-title><trans-title-group xml:lang="ru"><trans-title>Тонкие химические технологии</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2410-6593</issn><issn pub-type="epub">2686-7575</issn><publisher><publisher-name>MIREA – Russian Technological University (RTU MIREA).</publisher-name></publisher></journal-meta><article-meta><article-id custom-type="elpub" pub-id-type="custom">chemicallytech-1510</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>CHEMISTRY AND TECHNOLOGY OF ORGANIC SUBSTANCES</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>ХИМИЯ И ТЕХНОЛОГИЯ ОРГАНИЧЕСКИХ ВЕЩЕСТВ</subject></subj-group></article-categories><title-group><article-title>Synthesis of novel amphiphilic block-copolymers by means of ATRP</article-title><trans-title-group xml:lang="ru"><trans-title>Синтез новых амфифильных блок-сополимеров методом ATRP.</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Кирилина</surname><given-names>Ю. О.</given-names></name><name name-style="western" xml:lang="en"><surname>Кirilina</surname><given-names>Yu. О.</given-names></name></name-alternatives><bio xml:lang="ru"><p>кафедра Химии и технологии высокомолекулярных соединений им. С.С. Медведева, аспирант</p></bio><email xlink:type="simple">noemail@neicon.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Камп</surname><given-names>В. Ван</given-names></name><name name-style="western" xml:lang="en"><surname>Camp</surname><given-names>W. Van</given-names></name></name-alternatives><bio xml:lang="ru"><p>Department of Organic Chemistry, ст. науч. сотр</p></bio><email xlink:type="simple">noemail@neicon.ru</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Бакеева</surname><given-names>И. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Bakeeva</surname><given-names>I. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>кафедра Химии и технологии высокомолекулярных соединений им. С.С. Медведева, доцент</p></bio><email xlink:type="simple">noemail@neicon.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Дюпре</surname><given-names>Ф. Е.</given-names></name><name name-style="western" xml:lang="en"><surname>Du Prez</surname><given-names>F. E.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Department of Organic Chemistry, профессор</p></bio><email xlink:type="simple">noemail@neicon.ru</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Зубов</surname><given-names>В. П.</given-names></name><name name-style="western" xml:lang="en"><surname>Zubov</surname><given-names>V. P.</given-names></name></name-alternatives><bio xml:lang="ru"><p>кафедра Химии и технологии высокомолекулярных соединений им. С.С. Медведева, профессор</p></bio><email xlink:type="simple">noemail@neicon.ru</email><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>МИТХТ им. М.В. Ломоносова, 119571, Москва, пр-т Вернадского, д. 86</institution><country>Россия</country></aff><aff xml:lang="en"><institution>M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571</institution><country>Russian Federation</country></aff></aff-alternatives><aff xml:lang="ru" id="aff-2"><institution>Polymer Chemistry Research Group, Ghent University</institution><country>Belgium</country></aff><pub-date pub-type="collection"><year>2008</year></pub-date><pub-date pub-type="epub"><day>28</day><month>08</month><year>2008</year></pub-date><volume>3</volume><issue>4</issue><fpage>32</fpage><lpage>38</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Кirilina Y.О., Camp W.V., Bakeeva I.V., Du Prez F.E., Zubov V.P., 2008</copyright-statement><copyright-year>2008</copyright-year><copyright-holder xml:lang="ru">Кирилина Ю.О., Камп В.В., Бакеева И.В., Дюпре Ф.Е., Зубов В.П.</copyright-holder><copyright-holder xml:lang="en">Кirilina Y.О., Camp W.V., Bakeeva I.V., Du Prez F.E., Zubov V.P.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://www.finechem-mirea.ru/jour/article/view/1510">https://www.finechem-mirea.ru/jour/article/view/1510</self-uri><abstract><p>By means of ATRP the amphiphilic block-copolymers of polyisobornylacrylate-polyacrilic acid were produced. Kinetics of polymerization was investigated. Synthesized samples of polymers were characterized with molecular weight and polydispersity.</p></abstract><trans-abstract xml:lang="ru"><p>Методом квазиживой радикальной полимеризации с переносом атома (Atom Transfer Radical Polymerization, ATRP) получены амфифильные блок-сополимеры полиизоборнилакрилата–полиакриловой кислоты. Изучена кинетика полимеризации. Полученные образцы полимеров охарактеризованы по молекулярной массе и молекулярно-массовому распределению (ММР).</p></trans-abstract><kwd-group xml:lang="ru"><kwd>ATRP метод</kwd><kwd>амфифильные сополимеры</kwd><kwd>полиизоборнилакрилат</kwd><kwd>полиакриловая кислота</kwd><kwd>блок-сополимеры</kwd><kwd>кинетика полимеризации.</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Synthesis of poly(isobornyl acrylate) containing copolymers by atom transfer radical polymerization / B. Dervaux, W. Van Camp, L. Van Renterghem, F. E. Du Prez // J. Polym. Sci. Part A: Polym. Chem. – 2008. – Vol. 46. – P. 1649–1661.</mixed-citation><mixed-citation xml:lang="en">Synthesis of poly(isobornyl acrylate) containing copolymers by atom transfer radical polymerization / B. Dervaux, W. Van Camp, L. Van Renterghem, F. E. Du Prez // J. Polym. Sci. Part A: Polym. Chem. – 2008. – Vol. 46. – P. 1649–1661.</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Mori, H. New polymeric architectures with (meth)acrylic acid segments / H. Mori, A. H. E. Müller // Prog. Polym. Sci. – 2003. – Vol. 28. – P. 1403–1439.</mixed-citation><mixed-citation xml:lang="en">Mori, H. New polymeric architectures with (meth)acrylic acid segments / H. Mori, A. H. E. Müller // Prog. Polym. Sci. – 2003. – Vol. 28. – P. 1403–1439.</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">First nitroxide-mediated controlled free-radical polymerization of acrylic acid / L. Couvreur, C. Lefay, J. Belleney, B. Charleux, O. Guerret, S. Magnet // Macromolecules. – 2003. – Vol. 36. – P. 8260–8267.</mixed-citation><mixed-citation xml:lang="en">First nitroxide-mediated controlled free-radical polymerization of acrylic acid / L. Couvreur, C. Lefay, J. Belleney, B. Charleux, O. Guerret, S. Magnet // Macromolecules. – 2003. – Vol. 36. – P. 8260–8267.</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Living free-radical polymerization by reversible addition-fragmentation chain transfer: the RAFT process/ J. Chiefari, B. Y. K. Chong, F. Ercole, J. Krstina, J. Jeffery, T. P. T. Le, R. T. A. Mayadunne, G. F. Meijs, C. L. Moad, G. Moad, E. Rizzardo, S. H. Thang // Macromolecules. – 1998. – Vol. 31. – P. 5559–5562.</mixed-citation><mixed-citation xml:lang="en">Living free-radical polymerization by reversible addition-fragmentation chain transfer: the RAFT process/ J. Chiefari, B. Y. K. Chong, F. Ercole, J. Krstina, J. Jeffery, T. P. T. Le, R. T. A. Mayadunne, G. F. Meijs, C. L. Moad, G. Moad, E. Rizzardo, S. H. Thang // Macromolecules. – 1998. – Vol. 31. – P. 5559–5562.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Patten, T. E. Atom transfer radical polymerization and the synthesis of polymeric materials / T. E. Patten, K. Matyjaszewski // Adv. Mater. – 1998. – Vol. 10. – P. 901–915.</mixed-citation><mixed-citation xml:lang="en">Patten, T. E. Atom transfer radical polymerization and the synthesis of polymeric materials / T. E. Patten, K. Matyjaszewski // Adv. Mater. – 1998. – Vol. 10. – P. 901–915.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">First example of the atom transfer radical polymerization of an acidic monomer: direct synthesis of methacrylic acid copolymers in aqueous media / E. J. Ashford, V. Naldi, R. O’Dell, N. C. Billingham, S. P. Armes // Chem. Commun. – 1999. – Vol. 114 – P. 1285–1286.</mixed-citation><mixed-citation xml:lang="en">First example of the atom transfer radical polymerization of an acidic monomer: direct synthesis of methacrylic acid copolymers in aqueous media / E. J. Ashford, V. Naldi, R. O’Dell, N. C. Billingham, S. P. Armes // Chem. Commun. – 1999. – Vol. 114 – P. 1285–1286.</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Davis, K. A. Preparation of block copolymers of polystyrene and poly(t-butyl acrylate) of various molecular weights and architectures by atom transfer radical polymerization / K. A. Davis, B. Charleux, K. Matyjaszewski // J. Polym. Sci. Part A: Polym. Chem. – 2000. – Vol. 38. – P. 2274–2283.</mixed-citation><mixed-citation xml:lang="en">Davis, K. A. Preparation of block copolymers of polystyrene and poly(t-butyl acrylate) of various molecular weights and architectures by atom transfer radical polymerization / K. A. Davis, B. Charleux, K. Matyjaszewski // J. Polym. Sci. Part A: Polym. Chem. – 2000. – Vol. 38. – P. 2274–2283.</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Atom transfer polymerization of methyl methacrylate mediated by alkylpyridylmethanimine type ligands, copper(I) bromide, and alkyl halides in hydrocarbon solution / D. M. Haddleton, M. C. Crossman, B. H. Dana, D. J. Duncalf, A. M. Heming, D. Kukulj, A. Shooter. // Macromolecules. – 1999. – Vol. 32. – P. 2110–2119.</mixed-citation><mixed-citation xml:lang="en">Atom transfer polymerization of methyl methacrylate mediated by alkylpyridylmethanimine type ligands, copper(I) bromide, and alkyl halides in hydrocarbon solution / D. M. Haddleton, M. C. Crossman, B. H. Dana, D. J. Duncalf, A. M. Heming, D. Kukulj, A. Shooter. // Macromolecules. – 1999. – Vol. 32. – P. 2110–2119.</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Van Camp, W. Atom transfer radical polymerization of 1-ethoxyethyl (meth) acrylate: facile route toward near-monodisperse poly((meth) acrylic acid) / W. Van Camp, F. E. Du Prez // Macromolecules. – 2004. – Vol. 37. – P. 6673–6675.</mixed-citation><mixed-citation xml:lang="en">Van Camp, W. Atom transfer radical polymerization of 1-ethoxyethyl (meth) acrylate: facile route toward near-monodisperse poly((meth) acrylic acid) / W. Van Camp, F. E. Du Prez // Macromolecules. – 2004. – Vol. 37. – P. 6673–6675.</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Polymerization of methyl methacrylate with the carbon tetrachloride/dichlorotris- (triphenylphosphine)ruthenium(II)/methylaluminum bis(2,6-di-tert-butylphenoxide) initiating system: possibility of living radical polymerization / M. Kato, M. Kamigaito, M. Savamoto, T. Higashimura // Macromolecules. – 1995. – Vol. 28. – P. 1721–1723.</mixed-citation><mixed-citation xml:lang="en">Polymerization of methyl methacrylate with the carbon tetrachloride/dichlorotris- (triphenylphosphine)ruthenium(II)/methylaluminum bis(2,6-di-tert-butylphenoxide) initiating system: possibility of living radical polymerization / M. Kato, M. Kamigaito, M. Savamoto, T. Higashimura // Macromolecules. – 1995. – Vol. 28. – P. 1721–1723.</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Matyjaszewski, K. Atom transfer radical polymerization / K. Matyjaszewski, J. Xia // J. Chem. Rev. – 2001. – Vol. 101. – P. 2921–2990.</mixed-citation><mixed-citation xml:lang="en">Matyjaszewski, K. Atom transfer radical polymerization / K. Matyjaszewski, J. Xia // J. Chem. Rev. – 2001. – Vol. 101. – P. 2921–2990.</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Haddleton, D. M. Atom transfer radical polymerization of methyl methacrylate initiated by alkyl bromide and 2-pyridinecarbaldehyde imine copper(I) complexes/ D. M. Haddleton, C. B. Jasieczek, M. J. Hannon, A.J. Shotter // Macromolecules. – 1997. – Vol. 30. – P. 2190–2193.</mixed-citation><mixed-citation xml:lang="en">Haddleton, D. M. Atom transfer radical polymerization of methyl methacrylate initiated by alkyl bromide and 2-pyridinecarbaldehyde imine copper(I) complexes/ D. M. Haddleton, C. B. Jasieczek, M. J. Hannon, A.J. Shotter // Macromolecules. – 1997. – Vol. 30. – P. 2190–2193.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Controlled radical polymerization of methacrylic monomers in the presence of a bis(orthochelated) arylnickel(II) complex and different activated alkyl halides/ C. Granel, P. Dubois, R. Jerome, P. Teyssie // Macromolecules. – 1996. – Vol. 29. – P. 8576–8582.</mixed-citation><mixed-citation xml:lang="en">Controlled radical polymerization of methacrylic monomers in the presence of a bis(orthochelated) arylnickel(II) complex and different activated alkyl halides/ C. Granel, P. Dubois, R. Jerome, P. Teyssie // Macromolecules. – 1996. – Vol. 29. – P. 8576–8582.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Percec, V. "Living" radical polymerization of styrene initiated by arenesulfonyl chlorides and CuI(bpy)nCl / V. Percec, B. Barboiu // Macromolecules. – 1995. – Vol. 28. – P. 7970–7972.</mixed-citation><mixed-citation xml:lang="en">Percec, V. "Living" radical polymerization of styrene initiated by arenesulfonyl chlorides and CuI(bpy)nCl / V. Percec, B. Barboiu // Macromolecules. – 1995. – Vol. 28. – P. 7970–7972.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Braunecker, W. A. Controlled/living radical polymerization: features, developments, and perspectives / W. A. Braunecker, K. Matyjaszewski // Prog. Polym. Sci. – 2007. – Vol. 32. – P. 93–147.</mixed-citation><mixed-citation xml:lang="en">Braunecker, W. A. Controlled/living radical polymerization: features, developments, and perspectives / W. A. Braunecker, K. Matyjaszewski // Prog. Polym. Sci. – 2007. – Vol. 32. – P. 93–147.</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Block copolymers of vinyl ethers as thermo-responsive colloidal stabilizers of organic pigments in aqueous media / N. Bulychev, I. Arutunov, B. Verdonck, E.J.Goetals, F.E. Du Prez // Macromol. Chem. Phys. – 2004. – Vol. 205, № 18. – P. 2457–2463.</mixed-citation><mixed-citation xml:lang="en">Block copolymers of vinyl ethers as thermo-responsive colloidal stabilizers of organic pigments in aqueous media / N. Bulychev, I. Arutunov, B. Verdonck, E.J.Goetals, F.E. Du Prez // Macromol. Chem. Phys. – 2004. – Vol. 205, № 18. – P. 2457–2463.</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Application of thermo-responsive poly(methyl vinyl ether) containing copolymers in combination with ultrasonic treatment for pigment surface modification in pigment dispersions / N. Bulychev, O. Confortini, P. Kopold, K. Dirnberger, T. Schauer, F.E. Du Prez, V. Zubov, C.D. Eisenbach // Polymer. – 2007. – Vol. 48. – P. 2636–2643.</mixed-citation><mixed-citation xml:lang="en">Application of thermo-responsive poly(methyl vinyl ether) containing copolymers in combination with ultrasonic treatment for pigment surface modification in pigment dispersions / N. Bulychev, O. Confortini, P. Kopold, K. Dirnberger, T. Schauer, F.E. Du Prez, V. Zubov, C.D. Eisenbach // Polymer. – 2007. – Vol. 48. – P. 2636–2643.</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
