chemicallytechFine Chemical TechnologiesТонкие химические технологии2410-65932686-7575MIREA – Russian Technological University (RTU MIREA).10.32362/2410-6593-2018-13-2-5-20chemicallytech-137Research ArticleCHEMISTRY AND TECHNOLOGY OF MEDICINAL COMPOUNDS AND BIOLOGICALLY ACTIVE SUBSTANCESХИМИЯ И ТЕХНОЛОГИЯ ЛЕКАРСТВЕННЫХ ПРЕПАРАТОВ И БИОЛОГИЧЕСКИ АКТИВНЫХ СОЕДИНЕНИЙCOMPOUNDS OF BISMUTH AND ITS PORPHYRINE COMPLEXES: APPLICATION, STRUCTURE AND PROPERTIESСОЕДИНЕНИЯ ВИСМУТА И ЕГО КОМПЛЕКСЫ С ПОРФИРИНАМИ: ПРИМЕНЕНИЕ, СТРУКТУРА И СВОЙСТВАГоршковаА. С.GorshkovaA. S.

аспирант кафедры химии и технологии биологически активных соединений, медицинской и органической химии им. Н.А. Преображенского

119571, Россия, Москва, пр-т Вернадского, д. 86

Postgraduate Student of the N.A. Preobrazhenskiy Chair of Chemistry and Technology of Biologically Active Substances, Medical and Organic Chemistry,

86, Vernadskogo Pr., Moscow 119571, Russia

asgorsh@mail.ruhttps://orcid.org/0000-0003-1503-1427РумянцеваВ. Д.RumyantsevaV. D.

кандидат химических наук, старший научный сотрудник кафедры химии и технологии биологически активных соединений, медицинской и органической химии им. Н.А. Преображенского

119571, Россия, Москва, пр-т Вернадского, д. 86

старший научный сотрудник филиала Института радиотехники и электроники им. В.А. Котельникова РАН

141190, Фрязино, МО, пл. академика Введенского, д. 1

 

Ph.D. (Chemistry), Senior Researcher of the N.A. Preobrazhenskiy Chair of Chemistry and Technology of Biologically Active Substances, Medical and Organic Chemistry,

86, Vernadskogo Pr., Moscow 119571, Russia

Senior Researcher of V.A.

1, Akademika Vvedenskogo Sq., Moscow region, Fryazino 141190, Russia

noemail@neicon.ruМироновА. Ф.MironovA. F.

доктор химических наук, профессор кафедры химии и технологии биологически активных соединений, медицинской и органической химии им. Н.А. Преображенского

119571, Россия, Москва, пр-т Вернадского, д. 86

Dr.Sc. (Chemistry), Professor of the N.A. Preobrazhenskiy Chair of Chemistry and Technology of Biologically Active Substances, Medical and Organic Chemistry

86, Vernadskogo Pr., Moscow 119571, Russia

noemail@neicon.ruМосковский технологический университет (Институт тонких химических технологий им. М.В. Ломоносова)РоссияMoscow Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)Russian FederationМосковский технологический университет (Институт тонких химических технологий им. М.В. Ломоносова); Институт радиотехники и электроники им. В.А. Котельникова РАНРоссияMoscow Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies); Kotel’nikov Institute of Radioengineering and Electronics RASRussian Federation201828042018132520Copyright © Gorshkova A.S., Rumyantseva V.D., Mironov A.F., 20182018Горшкова А.С., Румянцева В.Д., Миронов А.Ф.Gorshkova A.S., Rumyantseva V.D., Mironov A.F.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.finechem-mirea.ru/jour/article/view/137

Bismuth and its compounds have been known since ancient times and now are widely used in practice in various fields. Bismuth use in medicine can be traced back to the Middle Ages, and its wide application is due to its very low toxicity - for most bismuth compounds it is less than for sodium chloride. Bismuth and its compounds, in particular salts, are used in medical practice in the treatment of diseases such as spirochetosis, gastric and duodenal ulcer, leishmaniasis and coronaviral infection, as well as in cancer therapy. In addition to solid preparations liquid peroral pharmaceutical forms have been developed for the treatment of diarrhea, colitis, ulcers etc. Bismuth preparations are used in stomatology for the treatment of inflammatory diseases of paradontium. The review considers the syntheses and properties of bismuth complexes with natural and synthetic porphyrins, which are used in medicine and other fields of science and technology. Considerable attention is paid to the structure features of bismuth porphyrins complexes, their dimeric structures, and the influence of various extra ligands. The counterion nature and structure make a substantial contribution in solving the problem of complexes stability. The central bismuth atom in these complexes extends far above the plane of the macrocycle due to the large ionic radius. Thus, the counterions action on the conformation, physicochemical properties and stability of metal porphyrins complexes is shown. A separate section is devoted to unique and interesting properties of bismuth porphyrins complexes, such as fluorescence and color variation of crystals.

Обзор посвящен использованию висмута и его соединений, в частности солей, в медицинской практике при лечении таких заболеваний, как спирохетозы, язвенная болезнь желудка и двенадцатиперстной кишки, а также в терапии рака. Наряду с твердыми препаратами разработаны жидкие пероральные лекарственные формы для лечения диареи, колитов, язв и др. Препараты висмута используются в стоматологии для лечения воспалительных заболеваний пародонта. Рассмотрены синтезы и свойства висмутовых комплексов с природными и синтетическими порфиринами, которые находят применение в медицине и иных областях науки и техники. Значительное внимание уделено особенностям строения висмутовых комплексов порфиринов, их пространственной структуре, влиянию стерических и электронодонорных эффектов, образованию димеров и влиянию различных экстралигандов. Так, показано действие противоионов на конформацию, физико-химические свойства и устойчивость висмутовых металлокомплексов порфиринов

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The authors declare that there are no conflicts of interest present.