chemicallytechFine Chemical TechnologiesТонкие химические технологии2410-65932686-7575MIREA – Russian Technological University (RTU MIREA).chemicallytech-1312Research ArticleCHEMISTRY AND TECHNOLOGY OF INORGANIC MATERIALSХИМИЯ И ТЕХНОЛОГИЯ НЕОРГАНИЧЕСКИХ МАТЕРИАЛОВHeterobimetallic palladium-based carboxylates as a new way to mixed- metal nanomaterialsГетерометаллические биядерные карбоксилаты металлов на основе палладия – новый путь к смешанно-металлическим наноматериаламКозицынаН. Ю.KozitsynaN. Yu.noemail@neicon.ruВаргафтикМ. Н.VargaftikM. N.noemail@neicon.ruНефедовС. Е.NefedovS. E.noemail@neicon.ruЯкушевИ. А.YakushevI. A.noemail@neicon.ruМоисеевИ. И.MoiseevI. I.noemail@neicon.ruИнститут общей и неорганической химии им. Н. С. Курнакова РАНRussian Federation200728062007231021Copyright © Kozitsyna N.Y., Vargaftik M.N., Nefedov S.E., Yakushev I.A., Moiseev I.I., 20072007Козицына Н.Ю., Варгафтик М.Н., Нефедов С.Е., Якушев И.А., Моисеев И.И.Kozitsyna N.Y., Vargaftik M.N., Nefedov S.E., Yakushev I.A., Moiseev I.I.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.finechem-mirea.ru/jour/article/view/1312

New synthetic approach to the preparation of palladium(II)-based heterobimetallic complexes was proposed. The complexes were prepared in high yields (85-95%) in single-crystalline form and structurally characterized by physicochemical methods, including X-ray structural analysis. All the complexes are built based on the structural motif [Pd(-OOCR)4M] (R = Me, tBu; M = Cu(II), Zn(II), Ni(II), Co(II), Mn(II), Ce(IV), Nd(III), Sm(III), Eu(III), Tm(III), Yb(III)). Reduction of the heterobimetallic complexes can produce new mixed-metal nanomaterials

Разработаны оригинальные синтетические подходы к получению биядерных гетерометаллических комплексов палладия, содержащих структурный мотив [Pd(-OOCR)4M] (R = Me, t-Bu; M = Cu(II), Zn(II), Ni(II), Co(II), Mn(II), Ce(IV), Nd(III), Sm(III), Eu(III), Tm(III), Yb(III)). Комплексы выделены с количественным выходом в монокристаллическом виде и охарактеризованы физико-химическими методами, в том числе данными рентгеноструктурного анализа. Смешанно-металлические наноматериалы могут быть получены восстановлением синтезированных комплексов.

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The authors declare that there are no conflicts of interest present.