chemicallytechFine Chemical TechnologiesТонкие химические технологии2410-65932686-7575MIREA – Russian Technological University (RTU MIREA).10.32362/2410-6593-2018-13-1-5-21chemicallytech-130Research ArticleANALYTICAL METHODS IN CHEMISTRY AND CHEMICAL TECHNOLOGYАНАЛИТИЧЕСКИЕ МЕТОДЫ В ХИМИИ И ХИМИЧЕСКОЙ ТЕХНОЛОГИИSENSORS BASED ON PHOTONIC CRYSTALSСЕНСОРЫ НА ОСНОВЕ ФОТОННЫХ КРИСТАЛЛОВКозловА. А.KozlovA. A.

Москва 119571, Россия

Ph.D. (Engineering), Associate Professor of the Chair of Physics and Technical Mechanics,

86, Vernadskogo Pr., Moscow 119571, Russia

anar42@yandex.ruГавриловЮ. А.GavrilovYu. A.

Москва 119334, Россия

Ph.D. (Chemistry), Research Associate, N.N. Semenov

4, Kosygin St., Moscow GSP-1, 119991, Russia

noemail@neicon.ruИвановА. В.IvanovA. V.

Москва 119991, Россия

Dr.Sc. (Chemistry), Associate Professor of the Chair of Analytical Chemistry, Chemical Faculty

Vorobyovy Gory, Moscow, 119899, Russia

noemail@neicon.ruАксеновА. С.AksenovA. S.

Москва 119571, Россия

Student of the Ya.K. Syrkin Chair of Physical Chemistry,

86, Vernadskogo Pr., Moscow 119571, Russia

noemail@neicon.ruФлидВ. Р.FlidV. R.

Москва 119571, Россия

Dr.Sc. (Chemistry), Professor, Head of the Ya.K. Syrkin Chair of Physical Chemistry

86, Vernadskogo Pr., Moscow 119571, Russia

noemail@neicon.ruМосковский технологический университет (Институт тонких химических технологий имени М.В. Ломоносова)РоссияMoscow Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)Russian FederationИнститут химической физики им. Н.Н. Семенова РАНРоссияN.N. Semenov Institute of Chemical Physics, Russian Academy of SciencesRussian FederationМосковский государственный университет им. М.В. ЛомоносоваРоссияLomonosov Moscow State UniversityRussian Federation201828022018131521Copyright © Kozlov A.A., Gavrilov Y.A., Ivanov A.V., Aksenov A.S., Flid V.R., 20182018Козлов А.А., Гаврилов Ю.А., Иванов А.В., Аксенов А.С., Флид В.Р.Kozlov A.A., Gavrilov Y.A., Ivanov A.V., Aksenov A.S., Flid V.R.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.finechem-mirea.ru/jour/article/view/130

Chemical sensors are one of the most demanded tools of modern analytical chemistry. Recently, devices based on the registration of color changes upon reflecting visible irradiation from the surface of so-called "photonic crystals" (PC) have begun to be used for analytical chemistry purposes. Some advantages of this method are the possibility of visual detection of substances, relatively high sensitivity, and the ability to change the properties of such sensors by varying the element base of the PC. The effect of various mechanical, electrical, optical, chemical and other factors on the objects under study leads to additional changes in the spectral responses from the PC surface with deposited materials. A sufficiently short response time allows the use of such sensors for the operational control of various substances with a high degree of hazard. In the long term, such devices can be used as test systems for the detection and analysis of a wide class of chemical and biological substances. This review is devoted to various types of sensors based on photonic crystals. It deals with: photonic crystals of natural and synthetic origin; various possible structures of PC; causes of the appearance of characteristic optical properties; detection of mechanical, thermal, electrical, magnetic and optical effects on the PC, as well as effects on organic compounds of various classes; areas of application of sensors based on PC.

Химические сенсоры являются одним из наиболее востребованных инструментов современной аналитической химии. В последнее время для аналитических целей стали использовать устройства, действие которых основано на регистрации изменения цвета при отражении видимого излучения от поверхности так называемых «фотонных кристаллов» (ФК). Преимуществами их применения являются возможность визуального детектирования соединений, относительно высокая чувствительность, а также возможность изменять свойства сенсоров путем варьирования элементной базы ФК. Кроме того, влияние различных механических, электрических, оптических, химических и других факторов на исследуемые объекты приводит к дополнительным изменениям спектральных откликов от поверхности ФК с нанесенными образцами. В перспективе подобные устройства можно использовать как тест-системы для обнаружения и анализа определенных классов химических соединений. Обзор посвящен различным типам сенсоров на основе фотонных кристаллов. В нем рассматриваются: фотонные кристаллы природного и синтетического происхождения; различные возможные структуры ФК; причины возникновения характерных оптических свойств; детектирование механических, тепловых, электрических, магнитных и оптических воздействий на ФК, а также воздействие на органические соединения различных классов; области применения сенсоров на основе ФК.

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The authors declare that there are no conflicts of interest present.